CO2 absorption by lithium silicate at room temperature

被引:117
作者
Essaki, K
Nakagawa, K
Kato, M
Uemoto, H
机构
[1] Toshiba Co Ltd, Environm Technol Lab, Ctr Corp Res & Dev, Kawasaki, Kanagawa 2128582, Japan
[2] Toshiba Ceram Co Ltd, Ctr Res & Dev, Kanagawa 2578566, Japan
关键词
lithium silicate; CO2; absorption; room temperature; humidity; water content;
D O I
10.1252/jcej.37.772
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Lithium silicate has been studied mainly as a CO2 absorbent at high temperatures of around 773 K. It has recently been observed that lithium silicate also absorbs atmospheric CO2 at room temperature. In this study, lithium silicate absorbent was packed in an absorption column and the effectiveness of this column was confirmed. Based on this result, the effectiveness of lithium silicate in absorbing atmospheric CO2 at room temperature was evaluated. It was found that humidity promoted absorption. This mechanism was examined and ascribed to the relationship between the water content in lithium silicate and CO2 absorption. In addition, the effectiveness of lithium silicate absorbent was compared with that of a commercially available absorbent (soda lime) under conditions of controlled humidity, and the superiority of lithium silicate was confirmed.
引用
收藏
页码:772 / 777
页数:6
相关论文
共 17 条
[1]  
AOKI I, 2002, NIHON KOUKU UCHU GAK, V50, P153
[2]  
Barin I., 1989, THERMOCHEMICAL DATA
[3]  
DallBauman LA, 1999, STUD SURF SCI CATAL, V120, P455
[4]   Acceleration effect of ternary carbonate on CO2 absorption rate in lithium zirconate powder [J].
Essaki, K ;
Nakagawa, K ;
Kato, M .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2001, 109 (10) :829-833
[5]  
GHOSH SK, 1969, J MINES METALS FUELS, V17, P391
[6]   New series of lithium containing complex oxides, lithium silicates, for application as a high temperature CO2 absorbent [J].
Kato, M ;
Nakagawa, K .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2001, 109 (11) :911-914
[7]   Carbon dioxide absorption by lithium orthosilicate in a wide range of temperature and carbon dioxide concentrations [J].
Kato, M ;
Yoshikawa, S ;
Nakagawa, K .
JOURNAL OF MATERIALS SCIENCE LETTERS, 2002, 21 (06) :485-487
[8]  
KATO M, 2001, NIHON ENERGY GAKKAI, V80, P781
[9]  
Matsuhashi R., 1992, Transactions of the Institute of Electrical Engineers of Japan, Part B, V112-B, P531
[10]   A novel method of CO2 capture from high temperature gases [J].
Nakagawa, K ;
Ohashi, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (04) :1344-1346