A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts

被引：495
作者：
Shultz, Abraham M.
Farha, Omar K.
Hupp, Joseph T. [1 ]
Nguyen, SonBinh T.
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 12期
关键词：
METAL-ORGANIC FRAMEWORK; MN2+ COORDINATION SITES; HYDROGEN STORAGE; BUILDING-BLOCKS; LARGE CHANNELS; SOLIDS; ADSORPTION; SEPARATION; CATALYSIS; BINDING;
D O I：
10.1021/ja900203f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
引用
收藏
页码：4204 / +
页数：3
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共 32 条
  • [1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS
    ABRAHAMS, BF
    HOSKINS, BF
    MICHAIL, DM
    ROBSON, R
    [J]. NATURE, 1994, 369 (6483) : 727 - 729
  • [2] Zeolite-like metal-organic frameworks as platforms for applications:: On metalloporphyrin-based catalysts
    Alkordi, Mohamed H.
    Liu, Yunling
    Larsen, Randy W.
    Eubank, Jarrod F.
    Eddaoudi, Mohamed
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) : 12639 - +
  • [3] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane
    Bae, Youn-Sang
    Farha, Omar K.
    Spokoyny, Alexander M.
    Mirkin, Chad A.
    Hupp, Joseph T.
    Snurr, Randall Q.
    [J]. CHEMICAL COMMUNICATIONS, 2008, (35) : 4135 - 4137
  • [4] Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks
    Bae, Youn-Sang
    Mulfort, Karen L.
    Frost, Houston
    Ryan, Patrick
    Punnathanam, Sudeep
    Broadbelt, Linda J.
    Hupp, Joseph T.
    Snurr, Randall Q.
    [J]. LANGMUIR, 2008, 24 (16) : 8592 - 8598
  • [5] A microporous metal-organic framework for gas-chromatographic separation of alkanes
    Chen, BL
    Liang, CD
    Yang, J
    Contreras, DS
    Clancy, YL
    Lobkovsky, EB
    Yaghi, OM
    Dai, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) : 1390 - 1393
  • [6] High H2 adsorption in a microporous metal-organic framework with open metal sites
    Chen, BL
    Ockwig, NW
    Millward, AR
    Contreras, DS
    Yaghi, OM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) : 4745 - 4749
  • [7] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation
    Cho, So-Hye
    Ma, Baoqing
    Nguyen, SonBinh T.
    Hupp, Joseph T.
    Albrecht-Schmitt, Thomas E.
    [J]. CHEMICAL COMMUNICATIONS, 2006, (24) : 2563 - 2565
  • [8] Pillared Porphyrin Homologous Series: Intergrowth in Metal-Organic Frameworks
    Choi, Eun-Young
    Barron, Paul M.
    Novotny, Richard W.
    Son, Hyun-Tak
    Hu, Chunhua
    Choe, Wonyoung
    [J]. INORGANIC CHEMISTRY, 2009, 48 (02) : 426 - 428
  • [9] Hydrogen storage in metal-organic frameworks
    Collins, David J.
    Zhou, Hong-Cai
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3154 - 3160
  • [10] Strong H2 binding and selective gas adsorption within the microporous coordination solid Mg3(O2C-C10H6-CO2)3
    Dinca, M
    Long, JR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (26) : 9376 - 9377
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