A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts

被引：498
作者：
Shultz, Abraham M.
Farha, Omar K.
Hupp, Joseph T. [1 ]
Nguyen, SonBinh T.
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 12期
关键词：
METAL-ORGANIC FRAMEWORK; MN2+ COORDINATION SITES; HYDROGEN STORAGE; BUILDING-BLOCKS; LARGE CHANNELS; SOLIDS; ADSORPTION; SEPARATION; CATALYSIS; BINDING;
D O I：
10.1021/ja900203f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
引用
收藏
页码：4204 / +
页数：3
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