Corresponding States of Structural Glass Formers

被引:194
|
作者
Elmatad, Yael S. [1 ]
Chandler, David [1 ]
Garrahan, Juan P. [2 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会;
关键词
DIELECTRIC-RELAXATION; SUPERCOOLED LIQUIDS; FORMING LIQUIDS; TEMPERATURE DEPENDENCES; LIGHT-SCATTERING; VISCOUS-FLOW; ISING-MODEL; DYNAMICS; VISCOSITY; THERMODYNAMICS;
D O I
10.1021/jp810362g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The variation with respect to temperature T of transport properties of 58 fragile structural glass-forming liquids (67 data sets in total) are analyzed and shown to exhibit a remarkable degree of universality. In particular, super-Arrhenius behaviors of all supercooled liquids appear to collapse to one parabola for which there is no singular behavior at any finite temperature. This behavior is bounded by an onset temperature T-o above which liquid transport has a much weaker temperature dependence. A similar collapse is also demonstrated over the smaller available range for existing numerical simulation data.
引用
收藏
页码:5563 / 5567
页数:5
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