The variation with respect to temperature T of transport properties of 58 fragile structural glass-forming liquids (67 data sets in total) are analyzed and shown to exhibit a remarkable degree of universality. In particular, super-Arrhenius behaviors of all supercooled liquids appear to collapse to one parabola for which there is no singular behavior at any finite temperature. This behavior is bounded by an onset temperature T-o above which liquid transport has a much weaker temperature dependence. A similar collapse is also demonstrated over the smaller available range for existing numerical simulation data.
机构:
Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
CNR ISC, I-00185 Rome, ItalyUniv Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
Crisanti, A.
Leuzzi, L.
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CNR ISC, I-00185 Rome, Italy
UOS Roma Kerberos, CNR IPCF, I-00185 Rome, ItalyUniv Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
Leuzzi, L.
Paoluzzi, M.
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UOS Roma Kerberos, CNR IPCF, I-00185 Rome, Italy
Univ Roma Tre, Dipartimento Fis, I-00184 Rome, ItalyUniv Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
机构:
Arizona State Univ, Dept Phys, POB 871504, Tempe, AZ 85287 USA
Arizona State Univ, Sch Mol Sci, POB 871504, Tempe, AZ 85287 USAArizona State Univ, Dept Phys, POB 871504, Tempe, AZ 85287 USA