Palladium-Catalyzed Intramolecular Hydroamination of Propargylic Carbamates and Carbamothioates

被引：47

作者：

Alamsetti, Santosh Kumar ^{[1
]}

Persson, Andreas K. A. ^{[1
]}

Backvall, Jan-E. ^{[1
]}

机构：

[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 05期

基金：

欧洲研究理事会; 瑞典研究理事会;

关键词：

OXIDATIVE CARBOCYCLIZATION; CONVENIENT SYNTHESIS; OXAZOLIDINONES; CYCLIZATION; ALCOHOLS; ISOCYANATES; ENALLENES; ALLENYNES; ARYL; 4-ALKYLIDENE-2-OXAZOLIDINONES;

D O I：

10.1021/ol5002279

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and simple methodology was developed for the synthesis of oxazolidinones, oxazolidinthiones, imidazolidinthiones, and imidazolidinones from the corresponding propargylic starting materials using Pd(OAc)(2) and n-Bu4NOAc as catalysts in DCE at room temperature.

引用

页码：1434 / 1437

页数：4

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