Recent Advances in Glycerol Catalytic Valorization: A Review

被引:128
作者
Checa, Manuel [1 ,2 ]
Nogales-Delgado, Sergio [1 ]
Montes, Vicente [1 ,2 ]
Encinar, Jose Maria [1 ]
机构
[1] Univ Extremadura, Dept Chem Engn & Phys Chem, Badajoz 06006, Spain
[2] Univ Extremadura, Univ Inst Water Climate Change & Sustainabil IACY, Badajoz 06006, Spain
关键词
glycerine; glycerol; active carbon; catalytic valorization; reforming; dehydration; hydrogenolysis; oxidation; PHOTOCATALYTIC HYDROGEN-PRODUCTION; SUPPORTED TRANSITION-METALS; SPINEL-DERIVED CATALYSTS; SELECTIVE HYDROGENOLYSIS; HIGHLY-EFFICIENT; CRUDE GLYCEROL; RENEWABLE HYDROGEN; SYNGAS PRODUCTION; MEMBRANE REACTOR; ETHYLENE-GLYCOL;
D O I
10.3390/catal10111279
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Once a biorefinery is ready to operate, the main processed materials need to be completely evaluated in terms of many different factors, including disposal regulations, technological limitations of installation, the market, and other societal considerations. In biorefinery, glycerol is the main by-product, representing around 10% of biodiesel production. In the last few decades, the large-scale production of biodiesel and glycerol has promoted research on a wide range of strategies in an attempt to valorize this by-product, with its transformation into added value chemicals being the strategy that exhibits the most promising route. Among them, C3 compounds obtained from routes such as hydrogenation, oxidation, esterification, etc. represent an alternative to petroleum-based routes for chemicals such as acrolein, propanediols, or carboxylic acids of interest for the polymer industry. Another widely studied and developed strategy includes processes such as reforming or pyrolysis for energy, clean fuels, and materials such as activated carbon. This review covers recent advances in catalysts used in the most promising strategies considering both chemicals and energy or fuel obtention. Due to the large variety in biorefinery industries, several potential emergent valorization routes are briefly summarized.
引用
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页码:1 / 41
页数:41
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