Research Progress on the Indirect Hydrogenation of Carbon Dioxide to Methanol

被引：107

作者：

Du, Xian-Long ^{[1
]}

Jiang, Zheng ^{[1
]}

Su, Dang Sheng ^{[2
,3
]}

Wang, Jian-Qiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Jialuo Rd 2019, Shanghai 201800, Peoples R China

[2] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China

[3] Max Planck Gesell, Fritz Haber Inst, Dept Inorgan Chem, Faradayweg 4-6, D-14195 Berlin, Germany

来源：

CHEMSUSCHEM | 2016年 / 9卷 / 04期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide; hydrogenation; intermediates; indirect; methanol; METHYL FORMATE; CATALYTIC-HYDROGENATION; CYCLIC CARBONATES; EFFICIENT HYDROGENATION; ALKYL FORMATES; FORMIC-ACID; CO2; HYDROGENOLYSIS; HYDROCARBONS; CAPTURE;

D O I：

10.1002/cssc.201501013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methanol is a sustainable source of liquid fuels and one of the most useful organic chemicals. To date, most of the work in this area has focused on the direct hydrogenation of CO2 to methanol. However, this process requires high operating temperatures (200-250 degrees C), which limits the theoretical yield of methanol. Thus, it is desirable to find a new strategy for the efficient conversion of CO2 to methanol at relatively low reaction temperatures. This Minireview seeks to outline the recent advances on the indirect hydrogenation of CO2 to methanol. Much emphasis is placed on discussing specific systems, including hydrogenation of CO2 derivatives (organic carbonates, carbamates, formates, cyclic carbonates, etc.) and cascade reactions, with the aim of critically highlighting both the achievements and remaining challenges associated with this field.

引用

页码：322 / 332

页数：11

共 62 条

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