Synthesis and characterisation of PCsp3P phosphine and phosphinite iridium complexes. Cyclometallation and dehydrogenation of a cyclohexyl ring

被引：40

作者：

Arunachalampillai, Athimoolam ^{[1
]}

Olsson, Daniel ^{[1
]}

Wendt, Ola F. ^{[1
]}

机构：

[1] Lund Univ, Dept Chem, S-22100 Lund, Sweden

来源：

DALTON TRANSACTIONS | 2009年 / 40期

基金：

瑞典研究理事会;

关键词：

DIPHOSPHINITO POCOP COMPLEXES; PCP PINCER COMPLEXES; METAL-CARBON BONDS; C-H; CRYSTAL-STRUCTURES; CATALYTIC DEHYDROGENATION; OXIDATIVE ADDITION; DINITROGEN; AMMONIA; ACTIVATION;

D O I：

10.1039/b910798c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cyclohexyl based pincer phosphine ligand undergoes cyclometalation with an iridium cyclooctadiene precursor to give a highly thermally stable iridium(III) complex where a C(sp(3))-H bond has been oxidatively added. This iridium(III) hydride complex is reduced with potassium to give a terminal iridium(I) dinitrogen complex with no tendency to dimerization. The corresponding cyclohexyl phosphinite ligand undergoes reversible dehydrogenation to give the aromatic cyclometalated iridium(III) hydride complex together with 3 equivalents of dihydrogen.

引用

页码：8626 / 8630

页数：5

共 48 条

[1]

[Anonymous], 2005, CRYS RED

[2]

Athimoolam A., 2008, ORGANOMETALLICS, V27, P4541

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