Selective Carbon-Carbon Bond Cleavage of Cyclopropylamine Derivatives

被引：124
作者：
Sokolova, Olga O. [1 ]
Bower, John F. [1 ,2 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
CHEMICAL REVIEWS | 2021年 / 121卷 / 01期
基金：
欧洲研究理事会;
关键词：
DONOR-ACCEPTOR CYCLOPROPANES; AMINO-SUBSTITUTED CYCLOPROPANES; INTERMOLECULAR 3+2 ANNULATION; RADICAL-CATION; N-DEALKYLATION; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CATALYZED OXIDATION; RING-EXPANSION; EASY ACCESS;
D O I：
10.1021/acs.chemrev.0c00166
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review summarizes synthetic developments reported from 1987 to 2019 that exploit C-C single bond cleavage of cyclopropylamine-based systems. The synthetic and mechanistic aspects of key methodologies are highlighted, and examples where aminocyclopropanes are exploited as key intermediates in multistep synthesis are also discussed. The review encompasses cases where aminocyclopropanes participate in polar reactions, pericyclic processes, radical-based reactions, and C-C bond activations.
引用
收藏
页码：80 / 109
页数：30
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