Effect of Inhibitor on Adsorption Behavior and Mechanism of Micro-Zone Corrosion on Carbon Steel

被引：10

作者：

Wang, Fengjuan ^{[1
]}

Zhang, Zhifeng ^{[1
]}

Wu, Shengping ^{[1
]}

Jiang, Jinyang ^{[1
]}

Chu, Hongyan ^{[2
]}

机构：

[1] Southeast Univ, Sch Mat Sci & Engn, Jiangsu Key Lab Construct Mat, Nanjing 211189, Jiangsu, Peoples R China

[2] Nanjing Forestry Univ, Coll Civil Engn, Nanjing 210037, Jiangsu, Peoples R China

来源：

MATERIALS | 2019年 / 12卷 / 12期

基金：

中国国家自然科学基金;

关键词：

carbon steel; EIS test; XPS; interfaces; inhibition mechanism; Q235; STEEL; PROTECTION; CHLORIDE; SURFACE; ACID; XPS; COATINGS; FILMS; IRON; EIS;

D O I：

10.3390/ma12121901

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new type of inhibitor is studied in this paper. Inhibition efficiency and adsorption behavior of an inhibitor film on the steel surface is tested via the electrochemical method and theoretical calculation to establish the adsorption model. Test results confirm that inhibition efficiency is improved with the addition of an inhibitor, and the inhibitor film is formed firmly by comparing the characteristic peaks of S and N. Moreover, the micro-zone corrosion progress of Fe in 3.5% invasive NaCl-simulated seawater environment is studied. The results further show that corrosion is initiated under the zone without the inhibitor film, while it is prevented under the protection of the film. By the experiments, it is shown that inhibitor can be adsorbed on the surface of steel stably and has excellent protection performance for reinforced rebar, which can be widely used in concrete structure.

引用

页数：10

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