Stimuli-Responsive Free-Standing Layer-By-Layer Films

被引：37
作者：
Hu, Xiaoran [1 ]
McIntosh, Ethan [1 ]
Simon, Marc G. [2 ]
Staii, Cristian [2 ]
Thomas, Samuel W., III [1 ]
机构：
[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA
[2] Tufts Univ, Dept Phys & Astron, Medford, MA 02155 USA
来源：
ADVANCED MATERIALS | 2016年 / 28卷 / 04期
基金：
美国国家科学基金会;
关键词：
POLYELECTROLYTE MULTILAYER FILMS; DRUG-DELIVERY; THIN-FILMS; 2-IMINOBIOTIN-LABELED POLY(ETHYLENEIMINE); INTERLAYER DIFFUSION; TRIGGERED RELEASE; MEMBRANES; ASSEMBLIES; SURFACES; CAPSULES;
D O I：
10.1002/adma.201504219
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Free-standing, stimuli-responsive polyelectrolyte multilayer films enabled by light-induced degradation of sacrificial compartments are introduced. Two examples are described: i) a triple responsive film that uses light, redox, and pH for different functions, and ii) different wavelengths of light for different functions. This approach to multiresponsive materials offers simple design and chemical synthesis while enabling different stimuli to perform separate functions in the same material.
引用
收藏
页码：715 / 721
页数：7
相关论文
共 64 条
  • [1] Layer-by-layer Nanoarchitectonics: Invention, Innovation, and Evolution
    Ariga, Katsuhiko
    Yamauchi, Yusuke
    Rydzek, Gaulthier
    Ji, Qingmin
    Yonamine, Yusuke
    Wu, Kevin C. -W.
    Hill, Jonathan P.
    [J]. CHEMISTRY LETTERS, 2014, 43 (01) : 36 - 68
  • [2] Rapid Release of Plasmid DNA from Surfaces Coated with Polyelectrolyte Multilayers Promoted by the Application of Electrochemical Potentials
    Aytar, Burcu S.
    Prausnitz, Mark R.
    Lynn, David M.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (05) : 2726 - 2734
  • [3] Stretch-Induced Biodegradation of Polyelectrolyte Multilayer Films for Drug Release
    Barthes, Julien
    Mertz, Damien
    Bach, Charlotte
    Metz-Boutigue, Marie-Helene
    Senger, Bernard
    Voegel, Jean-Claude
    Schaaf, Pierre
    Lavalle, Philippe
    [J]. LANGMUIR, 2012, 28 (38) : 13550 - 13554
  • [4] Layer-By-Layer-Assembled Capsules and Films for Therapeutic Delivery
    Becker, Alisa L.
    Johnston, Angus P. R.
    Caruso, Frank
    [J]. SMALL, 2010, 6 (17) : 1836 - 1852
  • [5] Synthesis of diblock copolymers bearing p-methoxyphenacyl side groups
    Bertrand, Olivier
    Gohy, Jean-Francios
    Fustin, Charles-Andre
    [J]. POLYMER CHEMISTRY, 2011, 2 (10) : 2284 - 2292
  • [6] Photolabile protecting groups and linkers
    Bochet, CG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (02): : 125 - 142
  • [7] Layer-by-Layer Assembly of Light-Responsive Polymeric Multilayer Systems
    Borges, Joao
    Rodrigues, Luisa C.
    Reis, Rui L.
    Mano, Joao F.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (36) : 5624 - 5648
  • [8] Molecular Interactions Driving the Layer-by-Layer Assembly of Multilayers
    Borges, Joao
    Mano, Joao F.
    [J]. CHEMICAL REVIEWS, 2014, 114 (18) : 8883 - 8942
  • [9] Layer-by-layer assembled stimuli-responsive nanoporous membranes
    Cho, Younghyun
    Lim, Jaehoon
    Char, Kookheon
    [J]. SOFT MATTER, 2012, 8 (40) : 10271 - 10278
  • [10] Controlling ion transport through multilayer polyelectrolyte membranes by derivatization with photolabile functional groups
    Dai, JH
    Balachandra, AM
    Lee, JI
    Bruening, ML
    [J]. MACROMOLECULES, 2002, 35 (08) : 3164 - 3170
1234567