Hydrophobic interactions between polymethacrylic acid and sodium laureth sulfate in aqueous solutions

被引：0

作者：

Yaremko, Z. M. ^{[1
]}

Fedushinskaya, L. B. ^{[1
]}

Burka, O. A. ^{[1
]}

Soltys, M. N. ^{[1
]}

机构：

[1] Ivan Franko Natl Univ, UA-79000 Lvov, Ukraine

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2014年 / 88卷 / 09期

关键词：

polymethacrylic acid; sodium laureth sulfate; binary solutions; hydrophobic interaction; association; DODECYLTRIMETHYLAMMONIUM BROMIDE; MOLECULAR-WEIGHT; PHASE-BEHAVIOR; COMPLEXES; MIXTURES; CARBOXYMETHYLCELLULOSE; COACERVATION; AGGREGATION; SURFACTANTS; ASSOCIATION;

D O I：

10.1134/S0036024414090313

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The role of hydrophobic interaction in the development of associative processes is demonstrated, based on the concentration dependences of the viscosity and pH of binary solutions of polymethacrylic acid as an anionic polyelectrolyte and sodium laureth sulfate as an anionic surfactant. It is found that the inflection point on the dependence of the difference between the pH values of binary solutions of polymethacrylic acid and sodium laureth sulfate on the polyelectrolyte concentration is a criterion for determining the predominant contribution from hydrophobic interaction, as is the inflection point on the dependence of pH of individual solutions of polymethacrylic acid on the polyelectrolyte concentration.

引用

页码：1510 / 1513

页数：4

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