Characterisation of the electrochemical behaviour of cerium implanted stainless steels

被引:27
作者
Abreu, CM [1 ]
Cristóbal, MJ [1 ]
Nóvoa, XR [1 ]
Pena, G [1 ]
Pérez, MC [1 ]
机构
[1] Univ Vigo, ETSEI, E-36200 Vigo, Spain
关键词
austenitic stainless steels; ce-implantation; cyclic voltammetry; XPS; EIS;
D O I
10.1016/S0013-4686(02)00058-0
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Passive layers formed on a Ce implanted stainless steel in alkaline media are studied to clarify its beneficial effect on stainless steel corrosion resistance. An important decrease in iron and chromium activity peaks is detected by electrochemical techniques. X-ray photoelectron spectroscopy (XPS) analysis shows passive film thickness decreasing together with changes in chemical composition. Cerium implantation modifies the conductivity properties of the passive Film, as it is inferred from EIS measurements. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2215 / 2222
页数:8
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