Silicone rubber/paraffin@silicon dioxide form-stable phase change materials with thermal energy storage and enhanced mechanical property

被引：89

作者：

Guo, Yongli ^{[1
]}

Yang, Wenbin ^{[1
]}

Jiang, Zhuoni ^{[1
]}

He, Fangfang ^{[1
]}

Zhang, Kai ^{[2
]}

He, Ren ^{[2
]}

Wu, Juying ^{[2
]}

Fan, Jinghui ^{[2
]}

机构：

[1] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China

[2] China Acad Engn Phys, Inst Syst Engn, Mianyang 621900, Sichuan, Peoples R China

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2019年 / 196卷

关键词：

Silicone rubber; Paraffin@SiO2 microencapsules; Form-stable phase change material mechanical properties; LATENT-HEAT; SHELL; ENCAPSULATION; CONDUCTIVITY; STABILITY; COMPOSITE; CAPSULES;

D O I：

10.1016/j.solmat.2019.03.034

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A kind of silicone rubber (SR)/paraffin (Pa)@silicon dioxide (SiO2) composite form-stable phase change material (PCM) was developed in this paper. Pa@SiO2 was obtained by choosing Pa as PCM core microencapsulated in SiO2 shell based on tetraethoxysilane (TEOS) and gamma-aminopropyl triethoxysilane (APTES) as precursors, then Pa@SiO2 microencapsules were embedded in SR matrix to fabricate SR/Pa@SiO2 composites. The SiO2 shell can provide a barrier for the melted Pa and meanwhile have reinforcing effect on SR as inorganic filler. The in-situ modification of SiO2 shell using APTES owing to the amino groups can not only prevent agglomeration, but also increase interfacial bonding between Pa@SiO2 with SR. The thermal and mechanical properties of the form stable PCMs were characterized by differential scanning calorimetry (DSC) and mechanical tests. The results showed that the thermal and mechanical properties of SR/Pa@SiO2 composites were better than those of SR/Pa and SR/Pa/SiO2. Leakage test was conducted by heating the prepared composites over the melting temperature of Pa. The SR/Pa@SiO2 composites were found as form-stable PCM with low leakage rate. The phase change latent heat of the SR/Pa@SiO2 composites was up to 92.39 J g(-1) and the composites can be used for thermal energy storage.

引用

页码：16 / 24

页数：9

共 37 条

[1] Preparation, Thermal Properties and Thermal Reliability of Form-Stable Paraffin/Polypropylene Composite for Thermal Energy Storage [J].

Alkan, Cemil ;

Kaya, Kemal ;

Sari, Ahmet .

JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2009, 17 (04) :254-258

[2] Polydimethylsiloxane thermal degradation - Part 1. Kinetic aspects [J].

Camino, G ;

Lomakin, SM ;

Lazzari, M .

POLYMER, 2001, 42 (06) :2395-2402

[3] Preparation and properties of graphene oxide-modified poly(melamine-formaldehyde) microcapsules containing phase change material n-dodecanol for thermal energy storage [J].

Chen, Zhonghua ;

Wang, Jianchuan ;

Yu, Fei ;

Zhang, Zhengguo ;

Gao, Xuenong .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (21) :11624-11630

[4] Functionalization of SBA-15 with APTES and characterization of functionalized materials [J].

Chong, ASM ;

Zhao, XS .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (46) :12650-12657

[5] Development and characterization of paraffin-based shape stabilized energy storage materials [J].

Ehid, Ryan ;

Fleischer, Amy S. .

ENERGY CONVERSION AND MANAGEMENT, 2012, 53 (01) :84-91

[6] Physical, mechanical, and biocompatibility evaluation of three different types of silicone rubber [J].

Fallahi, D ;

Mirzadeh, H ;

Khorasani, MT .

JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (10) :2522-2529

[7] Preparation, thermal properties and applications of shape-stabilized thermal energy storage materials [J].

Fang, Guiyin ;

Tang, Fang ;

Cao, Lei .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2014, 40 :237-259

[8] New approach for sol-gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor [J].

He, Fang ;

Wang, Xiaodong ;

Wu, Dezhen .

ENERGY, 2014, 67 :223-233

[9] Review on shell materials used in the encapsulation of phase change materials for high temperature thermal energy storage [J].

Jacob, Rhys ;

Bruno, Frank .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 48 :79-87

[10] Composite of wood-plastic and micro-encapsulated phase change material (MEPCM) used for thermal energy storage [J].

Jamekhorshid, A. ;

Sadrameli, S. M. ;

Barzin, R. ;

Farid, M. M. .

APPLIED THERMAL ENGINEERING, 2017, 112 :82-88

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