Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

被引：610

作者：

Hopkinson, Matthew N. ^{[1
]}

Sahoo, Basudev ^{[1
]}

Li, Jun-Long ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Organisch Chem Inst, NRW Grad Sch Chem, D-48149 Munster, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 14期

基金：

欧洲研究理事会;

关键词：

dual catalysis; photocatalysis; radical reactions; single-electron transfer; visible light; C-H ARYLATION; PHOTOINDUCED ELECTRON-TRANSFER; MULTIELECTRON CHARGE RELAYS; N-HETEROCYCLIC CARBENE; BOND-FORMING REACTIONS; VISIBLE-LIGHT; MOLECULAR-OXYGEN; AMINO-ACID; SYNTHETIC APPLICATIONS; DIARYLIODONIUM SALTS;

D O I：

10.1002/chem.201304823

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoredox activation of organic substrates with visible light is a powerful methodology that generates reactive radical species under very mild conditions. When combined with another catalytic process in a dual catalytic system, novel, visible-light-promoted transformations have been realized that do not proceed using either catalyst in isolation. In this minireview, the state of the art in organic reactions mediated by dual catalytic systems merging photoredox activation with organo-, acid or metal catalysis is discussed.

引用

页码：3874 / 3886

页数：13

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