Desymmetrizing hydroformylation with the aid of a planar chiral catalyst-directing group

被引：46
作者：
Breit, B [1 ]
Breuninger, D [1 ]
机构：
[1] Univ Freiburg, Inst Organ Chem & Biochem, Freiburg, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 33期
关键词：
D O I：
10.1021/ja0467364
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Desymmetrizing hydroformylation of bisalkenyl- and bisallylcarbinols could be achieved employing a chiral substrate-bound catalyst-directing group (o-DPPF) with excellent levels of diastereotopic alkene face and diastereotopic alkene group discrimination to give bifunctionalized chiral aldehydes in enantiomerically pure form. Copyright © 2004 American Chemical Society.
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页码：10244 / 10245
页数：2
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