A novel titanium tetrahalide-mediated carbon-carbon bond-forming reaction:: Regioselective synthesis of substituted (E,Z)-1,5-dihalo-1,4-dienes

被引：36

作者：

Kabalka, GW ^{[1
]}

Wu, ZZ

Ju, YH

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[2] Univ Tennessee, Dept Radiol, Knoxville, TN 37996 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 20期

关键词：

D O I：

10.1021/ol026507r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Reactions of aldehydes with 2 equiv of alkyne in the presence of TiX4 (X = Cl, Br) regioselectively generated 1,5-dihalo-1,4-dienes in moderate to good yields with high (E,Z)-stereoselectivity.

引用

页码：3415 / 3417

页数：3

共 52 条

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