Vapor-phase Catalytic Dehydration of 2,3-Butanediol into 3-Buten-2-ol over SC2O3

被引：18
作者：
Duan, Hailing [1 ]
Yamada, Yasuhiro [1 ]
Sato, Satoshi [1 ]
机构：
[1] Chiba Univ, Grad Sch Engn, Inage Ku, Chiba 2638522, Japan
来源：
CHEMISTRY LETTERS | 2014年 / 43卷 / 11期
关键词：
RARE-EARTH-OXIDES; INDIUM OXIDE; 1,5-PENTANEDIOL; ALCOHOLS; DIOLS;
D O I：
10.1246/cl.140662
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Vapor-phase catalytic dehydration of 2,3-butanediol (2,3-BDO) was investigated over rare earth oxide (RHO) catalysts as well as In2O3. In the dehydration of 2,3-BDO, 3-buten-2-ol (3B2OL) was produced together with 3-hydroxy-2-butanone (3H2BO), butanone (MEK), 2-methylpropanal (IBA), 2-methyl-1-propanol (IBO), etc. Sc2O3 and In2O3 showed higher 3B2OL selectivities than other REOs. In particular, Sc2O3 converted 2,3-BDO into 3B2OL with an excellent selectivity of 85.0% at 99.9% conversion.
引用
收藏
页码：1773 / 1775
页数：3
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