Two novel Pb(II)-organic frameworks based on polycarboxylate ligands: Syntheses, structures, and luminescent properties

被引：6
|
作者：
Zhang, Yanan [1 ]
Dang, Beijun [1 ]
Wang, Yu [2 ]
Huang, Wenhuan [1 ]
Yin, Haiju [1 ]
机构：
[1] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710021, Shaanxi, Peoples R China
[2] Xian Modern Chem Res Inst, Xian, Shaanxi, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷
基金：
中国国家自然科学基金;
关键词：
Pb-II-coordination framework; Organic-acid ligands; Network topology; Fluorescence; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURES; SERIES; ACID; POLYCATENATION; CONSTRUCTION; DIVERSITIES; COMPLEXES;
D O I：
10.1016/j.inoche.2015.08.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel Pb(II) complexes, {[Pb-1.5(BPIC)]center dot 0.25H(2)O) (1) and {[Pb(ADC) center dot (H2O)])(2), (H3BPTC = biphenyl-3,2' 5'-tricarboxylate, H(2)ADC = 1,3-Adamantanedicarboxylic acid) were successfully synthesized through varying the different polycarboxylate ligands. The compounds were structurally characterized by elemental analysis, IR and single-mystal X-ray diffraction. Compound 1 exhibits a 3D porous coordination framework, which possesses a new 3-nodal (5,6,8)-connected topology. Compound 2 shows a two-dimensional layer containing a 1D nanotube structure. In addition, compounds 1 and 2 exhibit high thermal stability and fluorescent properties in the solid state at room temperature. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：89 / 92
页数：4
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