Synthesis of lignin model compound containing a β-O-4 linkage

被引：6
|
作者：
Mukhtar, Asma [3 ]
Zaheer, Muhammad [3 ]
Saeed, Muhammad [1 ]
Voelter, Wolfgang [2 ]
机构：
[1] Lahore Univ Management Sci, Dept Chem, SBA Sch Sci & Engn, Lahore 54792, Pakistan
[2] Eberhard Karls Univ Tubingen, Interfak Inst Biochem, Hoppe Seyler Str 4, D-72076 Tubingen, Germany
[3] Lahore Univ Management Sci, Dept Chem, SBA Sch Sci & Engn, Lahore 54792, Pakistan
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2017年 / 72卷 / 02期
关键词：
aromatic raw material; bio-waste; lignin; model compounds; beta-O-4; linkage; CATALYTIC CONVERSION; ARYL ETHERS; CHEMICALS; BIOMASS; CELLULOSE; FUELS; HYDROGENOLYSIS; TRANSFORMATION; HYDROLYSIS; MECHANISM;
D O I：
10.1515/znb-2016-0201
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Development of catalysts for efficient conversion of lignin polymer to value- added materials requires appropriately- functionalized lignin model compounds. The predominant structural feature of lignin biopolymer is an extensive network of beta-O-4 linkages. Access to large amounts of a model compound containing the beta-O-4 linkage is crucial for the valorisation of lignin biopolymer to aromatic raw materials. Starting from commercially available vanillin, synthesis of dilignol model compound, containing a beta-O-4 linkage, is accomplished in good overall yield.
引用
收藏
页码：119 / 124
页数：6
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