Helical Packing of Nanoparticles Confined in Cylindrical Domains of a Self-Assembled Block Copolymer Structure

被引：56
作者：
Sanwaria, Sunita [1 ]
Horechyy, Andriy [2 ]
Wolf, Daniel [3 ]
Chu, Che-Yi [4 ]
Chen, Hsin-Lung [4 ]
Formanek, Petr [2 ]
Stamm, Manfred [2 ]
Srivastava, Rajiv [1 ]
Nandan, Bhanu [1 ]
机构：
[1] Indian Inst Technol Delhi, Dept Text Technol, New Delhi 110016, India
[2] Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany
[3] Tech Univ Dresden, Inst Struct Phys, Triebenberg Lab, D-01062 Dresden, Germany
[4] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 34期
关键词：
block copolymers; helical packing; nanoobjects; nanoparticles; self-assembly; CIRCULAR-DICHROISM; MIXTURES; LOCATION; CHAINS; GOLD;
D O I：
10.1002/anie.201403565
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Theoretical models predict that a variety of self-assembled structures of closely packed spherical particles may result when they are confined in a cylindrical domain. In the present work we demonstrate for the first time that the polymer-coated nanoparticles confined in the self-assembled cylindrical domains of a block copolymer pack in helical morphology, where we can isolate individual fibers filled with helically arranged nanoparticles. This finding provides unique possibilities for fundamental as well as application-oriented research in similar directions.
引用
收藏
页码：9090 / 9093
页数：4
相关论文
共 50 条
  • [41] Self-assembled structures in blends of block copolymer A-block-B with homopolymer A:: SAXS and SANS study
    Holoubek, Jaroslav
    Baldrian, Josef
    Lednicky, Frantisek
    Malkova, Sarka
    Lal, Jyotsana
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (20) : 1834 - 1841
  • [42] Self-assembled liposomal nanoparticles in photodynamic therapy
    Sadasivam, Magesh
    Avci, Pinar
    Gupta, Gaurav K.
    Lakshmanan, Shanmugamurthy
    Chandran, Rakkiyappan
    Huang, Ying-Ying
    Kumar, Raj
    Hamblin, Michael R.
    EUROPEAN JOURNAL OF NANOMEDICINE, 2013, 5 (03) : 115 - 129
  • [43] Spatial Control of the Self-assembled Block Copolymer Domain Orientation and Alignment on Photopatterned Surfaces
    Kim, Ji Yeon
    Liu, Philip
    Maher, Michael J.
    Callan, Devon H.
    Bates, Christopher M.
    Carlson, Matthew C.
    Asano, Yusuke
    Blachut, Gregory
    Rettner, Charles T.
    Cheng, Joy Y.
    Sunday, Daniel F.
    Kline, R. Joseph
    Sanders, Daniel P.
    Lynd, Nathaniel A.
    Ellison, Christopher J.
    Willson, C. Grant
    Baiz, Carlos R.
    ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (20) : 23399 - 23409
  • [44] Electrogenerated Chemiluminescence of Iridium-Containing ROMP Block Copolymer and Self-Assembled Micelles
    Tefashe, Ushula M.
    Metera, Kimberly L.
    Sleiman, Hanadi F.
    Mauzeroll, Janine
    LANGMUIR, 2013, 29 (41) : 12866 - 12873
  • [45] Self-assembled block copolymer templates for atomic layer deposition: The effect of processing solvent
    Moshonov, Moshe
    Kauffmann, Yaron
    Frey, Gitti L.
    POLYMER, 2016, 105 : 214 - 220
  • [46] Self-assembled nanoformulation of methylprednisolone succinate with carboxylated block copolymer for local glucocorticoid therapy
    Kamalov, Marat, I
    Trinh Dang
    Petrova, Natalia, V
    Laikov, Alexander, V
    Duong Luong
    Akhmadishina, Rezeda A.
    Lukashkin, Andrei N.
    Abdullin, Timur, I
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2018, 164 : 78 - 88
  • [47] Degradable Block Copolymer Nanoparticles Synthesized by Polymerization-Induced Self-Assembly
    Zhang, Shudi
    Li, Ruoyu
    An, Zesheng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (12)
  • [48] Electrochemically Triggered Selective Adsorption of Biotemplated Nanoparticles on Self-Assembled Organometallic Diblock Copolymer Thin Films
    Eloi, Jean-Charles
    Jones, Sarah E. Ward
    Poor, Veronika
    Okuda, Mitsuhiro
    Gwyther, Jessica
    Schwarzacher, Walther
    ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (15) : 3273 - 3278
  • [49] Co-assembly of helical β3-peptides: a self-assembled analogue of a statistical copolymer
    Buchanan, Claire
    Garvey, Christopher J.
    Perlmutter, Patrick
    Mechler, Adam
    PURE AND APPLIED CHEMISTRY, 2017, 89 (12) : 1809 - 1816
  • [50] Dot Nanopattern Self-Assembled from Rod-Coil Block Copolymer on Substrate
    Sun, Bo
    Xu, Zhanwen
    Tang, Zhengmin
    Cai, Chunhua
    Lin, Jiaping
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2020, 221 (18)
12345