Chemoselective Carbon-Carbon Cross-Coupling via Palladium-Catalyzed Copper-Mediated C-S Cleavage of Disulfides

被引：53
|
作者：
Quan, Zheng-Jun [1 ,2 ]
Lv, Ying [1 ,2 ]
Jing, Fu-Qiang [1 ,2 ]
Jia, Xiao-Dong [1 ,2 ]
Huo, Cong-De [1 ,2 ]
Wang, Xi-Cun [1 ,2 ]
机构：
[1] Minist Educ, Lab Ecoenvironm Related Polymer Mat, Beijing, Peoples R China
[2] Northwest Normal Univ, Coll Chem & Chem Engn, Gansu Key Lab Polymer Mat, Lanzhou 730070, Gansu, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 2-3期
关键词：
alkynes; arylboronic acids; CS bond cleavage; diheteroaryl disulfides; Liebeskind-Srogl cross coupling; ARYL METHYL SULFIDES; BORONIC ACIDS; BOND FORMATION; THIOL ESTERS; REGIOSELECTIVE SYNTHESIS; ELECTROPHILIC ANNULATION; EFFICIENT SYNTHESIS; ORGANIC DISULFIDES; PEPTIDYL KETONES; BIGINELLI-TYPE;
D O I：
10.1002/adsc.201300776
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An efficient method for carbon-carbon bond formation is described. The process employs the palladium-catalyzed copper-mediated cross-coupling of diheteroaryl disulfides with arylboronic acids or alkynes to deliver CC coupling products through unreactive CS bond cleavage. The scope of the coupling reactions, including both the disulfides and arylboronic acids or alkynes, are documented.
引用
收藏
页码：325 / 332
页数：8
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