Distinct Temperature-Dependent CO2 Sorption of Two Isomeric Metal-Organic Frameworks

被引：30
作者：
Liu, Bo [1 ]
Shi, Jingtao [1 ]
Yue, Ke-Fen [1 ]
Li, Dong-Sheng [2 ]
Wang, Yao-Yu [1 ]
机构：
[1] Northwest Univ, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Peoples R China
[2] China Three Gorges Univ, Coll Mat & Chem Engn, Inst Mat Res, Yichang 443002, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 04期
关键词：
ZEOLITIC IMIDAZOLATE FRAMEWORKS; SELECTIVE GAS-ADSORPTION; PORE-SIZE; SEPARATION; CAPTURE; LIGAND; MOFS; FUNCTIONALIZATION; THERMODYNAMICS; EFFICIENT;
D O I：
10.1021/cg500121f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two isomeric metal-organic frameworks, consisting of Co-triazolate layers and positional isomeric dicarboxylate pillars, both show distinct temperature-dependent CO2 sorption behaviors. Because of the pores functionalized by amino groups, both materials have high CO2 uptake and highly selective sorption of CO2 over CH4 and N-2.
引用
收藏
页码：2003 / 2008
页数：6
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