Partially nanowire-structured TiO2 electrode for dye-sensitized solar cells

被引:53
作者
Suzuki, Yoshikazu [1 ]
Ngamsinlapasathian, Supachai [1 ]
Yoshida, Ryuhei [1 ]
Yoshikawa, Susumu [1 ]
机构
[1] Kyoto Univ, Inst Adv Energy, Kyoto 6110011, Japan
来源
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2006年 / 4卷 / 03期
关键词
TiO2; nanowire; partially nanowire-structured TiO2; dye-sensitized solar cell; electron expressway concept;
D O I
10.2478/s11532-006-0015-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Partially nanowire-structured TiO2 was prepared by a hydrothermal processing followed by calcination in air. The hydrogen titanate powder as-synthesized was calcined at 300 degrees C for 4 h to obtain the partially nanowire-structured TiO2. A dye-sensitized solar cell (DSC) with a film thickness of 5.6 Mm, fabricated using the partially nanowire-structured TiO2 showed better performance than using a fully nanowire-structured TiO2 or a conventional equi-axed TiO2 nanopowder. The short-circuit current density (J(SC)), the open-circuit voltage (V-OC), the fill factor (FF) and the overall efficiency (eta) are 11.9 mA/cm(2), 0.754 V, 0.673 and 6.01 %, respectively. The effects of one-dimensional nanostructure and electron expressway concept are discussed. (C) Versita Warsaw and Springer-Verlag Berlin Heidelberg. All rights reserved.
引用
收藏
页码:476 / 488
页数:13
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