Chiral arene ruthenium complexes as asymmetric Diels-Alder catalysts

被引：88

作者：

Davies, DL

Fawcett, J

Garratt, SA

Russell, DR

机构：

[1] Department of Chemistry, University of Leicester, Leicester

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 15期

关键词：

D O I：

10.1039/a703386i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cation [RuCl(L)(eta(6)-mes)](+) [L = 4-isopropyl-2-(2-pyridyl)-1,3-oxazoline] is synthesised diastereoselectively; treatment with AgSbF6 gives a dication which is an enantioselective catalyst for the asymmetric Diels-Alder reaction between methacrolein and cyclopentadiene.

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页码：1351 / 1352

页数：2

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