Semi-synthesis of several stigmasterol saponins

被引：8

作者：

Li Chun-Xia ^{[1
]}

Guo Tian-Tian ^{[1
]}

Wang Peng ^{[1
]}

Guan Hua-Shi ^{[1
]}

Li Ying-Xia ^{[1
]}

机构：

[1] Ocean Univ China, Key Lab Marine Drugs, Minist Educ China, Inst Marine Drug & Food, Qingdao 266003, Shandong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2006年 / 24卷 / 07期

关键词：

stigmasterol; saponins; glycosylation;

D O I：

10.1002/cjoc.200690174

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several stigamasterol saponins were concisely synthesized. Namely, four monosaccharide (glucopyranose. galactopyranose, xylopyranose, 2-acetamido-2-deoxy-alpha-D-glucopyranose), lactopyranose and chacotriose were coupled with 3-OH of stigmasterol. All the compounds were identified by NMR. IR and high resolusion MS.

引用

页码：917 / 922

页数：6

共 50 条

[21] Short-step synthesis of chenodiol from stigmasterol [J].

Uekawa, T ;

Ishigami, K ;

Kitahara, T .

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY, 2004, 68 (06) :1332-1337

[22] Synthesis of 22,23-epoxyecdysteroids from stigmasterol [J].

Kovganko, NV ;

Survilo, VL .

CHEMISTRY OF NATURAL COMPOUNDS, 2001, 37 (02) :154-161

[23] Synthesis of L-arabinopyranose containing hederagenin saponins [J].

Plé, K ;

Chwalek, M ;

Voutquenne-Nazabadioko, L .

TETRAHEDRON, 2005, 61 (18) :4347-4362

[24] Synthesis of immunostimulatory saponins: A sweet challenge for carbohydrate chemists [J].

Marin, Oscar Javier Gamboa ;

Heis, Floriane ;

Gauthier, Charles .

CARBOHYDRATE RESEARCH, 2023, 530

[25] Synthesis of dihydrodiosgenin glycosides as mimetics of bidesmosidic steroidal saponins [J].

Suhr, R ;

Lahmann, M ;

Oscarson, S ;

Thiem, J .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (20) :4003-4011

[26] Synthesis and Evaluation of Saponins with All-Nitrogenated Sugars [J].

Kage, Ayaha ;

Okuyama, Yuya ;

Kato, Erina ;

Matagawa, Tomoe ;

Kawano, Sayaka ;

Simizu, Siro ;

Chida, Noritaka ;

Okamura, Toshitaka ;

Sato, Takaaki .

SYNLETT, 2024, 35 (04) :427-430

[27] Synthesis of 22,23-Epoxyecdysteroids from Stigmasterol [J].

N. V. Kovganko ;

V. L. Survilo .

Chemistry of Natural Compounds, 2001, 37 :154-161

[28] Impact of several variables on the microwave extraction of Chenopodium Quinoa willd saponins [J].

Gianna, Vicente ;

Manuel Montes, Juan ;

Luis Calandri, Edgardo ;

Alberto Guzman, Carlos .

INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2012, 47 (08) :1593-1597

[29] Applications of glycosyltransferases in synthesis of triterpenoid saponins [J].

Li N. ;

Li C. .

Huagong Xuebao/CIESC Journal, 2019, 70 (10) :3869-3879

[30] Synthesis and Cytotoxicity of 28a-Homothiolupanes and 28a-Homothiolupane Saponins [J].

Sidoryk, Katarzyna ;

Korda, Anna ;

Rarova, Lucie ;

Oklestkova, Jana ;

Pakulski, Zbigniew ;

Strnad, Miroslav ;

Cmoch, Piotr ;

Gwardiak, Katarzyna ;

Karczewski, Romuald .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (02) :373-383

← 1 2 3 4 5 →