Combined effects of Sepiolite and Cloisite 30B on morphology and properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/polylactide blends

被引:22
作者
Zembouai, Idris [1 ,2 ]
Kaci, Mustapha [1 ]
Zaidi, Lynda [1 ]
Bruzaud, Stephane [3 ]
机构
[1] Univ Abderrahmane Mira, LMPA, Fac Technol, Bejaia 06000, Algeria
[2] Univ Saad Dahlab Blida1, Dept Genie Procedes, Fac Technol, BP 270,Route Soumaa, Blida 09000, Algeria
[3] Univ Bretagne Sud, IRDL, UMR CNRS 6027, Rue St Maude, F-56321 Lorient, France
关键词
Biopolymers; Polymer blend; Sepiolite; Cloisite; 30B; Properties; MODIFIED MONTMORILLONITE; NANOWHISKERS COMPOSITES; REPROCESSING CYCLES; PHYSICAL-PROPERTIES; 15A NANOCOMPOSITES; BARRIER PROPERTIES; THERMAL-STABILITY; PHBV/PLA BLENDS; COMPATIBILIZER; DEGRADATION;
D O I
10.1016/j.polymdegradstab.2018.04.017
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The aim of the work was to investigate the combined effect of Sepiolite and Cloisite 30B on the morphology and properties of PHBV/PLA 50/50 w/w blend. Scanning electron microscopic analysis showed that the morphology of PHBV/PLA blend was relatively regular and homogeneous in the presence of Cloisite 30B and Sepiolite compared to the virgin blend, indicating a better compatibility between the two base polymers. The thermal stability of PHBV/PLA blend was enhanced by the clay fillers. Modulus and hardness were also increased in comparison with the virgin blend. The rheological measurements showed a significant increase in both the complex viscosity and storage modulus of the filled blend due to interactions between the clays fillers and the PHBV/PLA blend. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:47 / 52
页数:6
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