Combined effects of Sepiolite and Cloisite 30B on morphology and properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/polylactide blends

被引:22
作者
Zembouai, Idris [1 ,2 ]
Kaci, Mustapha [1 ]
Zaidi, Lynda [1 ]
Bruzaud, Stephane [3 ]
机构
[1] Univ Abderrahmane Mira, LMPA, Fac Technol, Bejaia 06000, Algeria
[2] Univ Saad Dahlab Blida1, Dept Genie Procedes, Fac Technol, BP 270,Route Soumaa, Blida 09000, Algeria
[3] Univ Bretagne Sud, IRDL, UMR CNRS 6027, Rue St Maude, F-56321 Lorient, France
关键词
Biopolymers; Polymer blend; Sepiolite; Cloisite; 30B; Properties; MODIFIED MONTMORILLONITE; NANOWHISKERS COMPOSITES; REPROCESSING CYCLES; PHYSICAL-PROPERTIES; 15A NANOCOMPOSITES; BARRIER PROPERTIES; THERMAL-STABILITY; PHBV/PLA BLENDS; COMPATIBILIZER; DEGRADATION;
D O I
10.1016/j.polymdegradstab.2018.04.017
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The aim of the work was to investigate the combined effect of Sepiolite and Cloisite 30B on the morphology and properties of PHBV/PLA 50/50 w/w blend. Scanning electron microscopic analysis showed that the morphology of PHBV/PLA blend was relatively regular and homogeneous in the presence of Cloisite 30B and Sepiolite compared to the virgin blend, indicating a better compatibility between the two base polymers. The thermal stability of PHBV/PLA blend was enhanced by the clay fillers. Modulus and hardness were also increased in comparison with the virgin blend. The rheological measurements showed a significant increase in both the complex viscosity and storage modulus of the filled blend due to interactions between the clays fillers and the PHBV/PLA blend. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:47 / 52
页数:6
相关论文
共 36 条
[1]   Processing, Properties, and Applications of Polymer Nanocomposites Based on Layer Silicates: A Review [J].
Alateyah, A. I. ;
Dhakal, H. N. ;
Zhang, Z. Y. .
ADVANCES IN POLYMER TECHNOLOGY, 2013, 32 (04)
[2]   Effect of chitosan and catechin addition on the structural, thermal, mechanical and disintegration properties of plasticized electrospun PLA-PHB biocomposites [J].
Arrieta, M. P. ;
Lopez, J. ;
Lopez, D. ;
Kenny, J. M. ;
Peponi, L. .
POLYMER DEGRADATION AND STABILITY, 2016, 132 :145-156
[3]   Synergistic Reinforcement of Highly Oriented Poly(propylene) Tapes by Sepiolite Nanoclay [J].
Bilotti, Emiliano ;
Deng, Hua ;
Zhang, Rui ;
Lu, Dun ;
Bras, Wim ;
Fischer, Hartmut R. ;
Peijs, Ton .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2010, 295 (01) :37-47
[4]   Thermal degradation and (nano)mechanical behavior of layered silicate reinforced poly(3-hydroxybutyrate-co-3-hydroxyvalerate) nanocomposites [J].
Bruzaud, Stephane ;
Bourmaud, Alain .
POLYMER TESTING, 2007, 26 (05) :652-659
[5]   Thermal behavior, dynamic mechanical properties and rheological properties of poly(butylene succinate) composites filled with nanometer calcium carbonate [J].
Chen, Rong-yuan ;
Zou, Wei ;
Zhang, Hai-chen ;
Zhang, Gui-zhen ;
Yang, Zhi-tao ;
Jin, Gang ;
Qu, Jin-ping .
POLYMER TESTING, 2015, 42 :160-167
[6]   Synergistic effect of compatibilizer and sepiolite on the morphology of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/poly(butylene succinate) blends [J].
Chikh, Amirouche ;
Benhamida, Aida ;
Kaci, Mustapha ;
Pillin, Isabelle ;
Bruzaud, Stephane .
POLYMER TESTING, 2016, 53 :19-28
[7]   Nanocomposites of PLA and PCL based on montmorillonite and sepiolite [J].
Fukushima, K. ;
Tabuani, D. ;
Camino, G. .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2009, 29 (04) :1433-1441
[8]   Morphology and molten-state rheology of polylactide and polyhydroxyalkanoate blends [J].
Gerard, Thibaut ;
Budtova, Tatiana .
EUROPEAN POLYMER JOURNAL, 2012, 48 (06) :1110-1117
[9]   Effect of the addition of sepiolite on the morphology and properties of melt compounded PHBV/PLA blends [J].
Gonzalez-Ausejo, Jennifer ;
Gamez-Perez, Jose ;
Balart, Rafael ;
Maria Lagaron, Jose ;
Cabedo, Luis .
POLYMER COMPOSITES, 2019, 40 (E156-E168) :E156-E168
[10]   Fabrication and Characterization of PLA/PHBV-Chitin Nanocomposites and Their Foams [J].
Guan, Qi ;
Naguib, Hani E. .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2014, 22 (01) :119-130