Nickel-metalated porous organic polymer for Suzuki-Miyaura cross-coupling reaction

被引：20

作者：

Dong, Ying ^{[1
]}

Jv, Jing-Jing ^{[1
]}

Li, Yue ^{[1
]}

Li, Wen-Han ^{[1
]}

Chen, Yun-Qi ^{[1
]}

Sun, Qian ^{[1
]}

Ma, Jian-Ping ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Minist Educ, Univ Shandong,Key Lab Mol & Nano Probes, Coll Chem Chem Engn & Mat Sci,Collaborat Innovat, Jinan 250014, Shandong, Peoples R China

来源：

RSC ADVANCES | 2019年 / 9卷 / 35期

基金：

中国国家自然科学基金;

关键词：

ALPHA-DIIMINE CATALYSTS; N-HETEROCYCLIC CARBENE; HETEROGENEOUS CATALYSTS; NANOPARTICLES; ETHYLENE; CRYSTALLINE; PALLADIUM; ALCOHOLS; BROMIDES; ADVANCE;

D O I：

10.1039/c9ra03679b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new Ni(ii)-alpha-diimine-based porous organic polymer, namely Ni(ii)-alpha-diimine-POP, was constructed in high yield via the Sonogashira coupling reaction between the metallo-building block of Ni(ii)-alpha-diimine and 1,3,5-triethynylbenzene. Besides the high thermal and chemical stability, the obtained Ni(ii)-alpha-diimine-POP can be a highly active reusable heterogeneous catalyst to promote the Suzuki-Miyaura coupling reaction. The obtained results indicate that the Ni(ii)-alpha-diimine-POP herein is a promising sustainable alternative to the Pd-based catalysts for catalysing the C-C formation in a heterogeneous way.

引用

页码：20266 / 20272

页数：7

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