Recent Advances in Metal-catalyzed Alkylation, Alkenylation and Alkynylation of Indole/indoline Benzenoid Nucleus

被引：52
|
作者：
Pradhan, Sourav [1 ]
De, Pinaki Bhusan [1 ]
Shah, Tariq A. [1 ,2 ]
Punniyamurthy, Tharmalingam [1 ]
机构：
[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India
[2] Govt Srinagar Womens Coll, Zakura Srinagar 190006, India
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2020年 / 15卷 / 24期
关键词：
indoles; site-selective; C− C coupling; metal; H activation; C-H ACTIVATION; ALCOHOLS DIRECT ACCESS; N-CARBAMOYL INDOLINES; DIRECTING-GROUP; REGIOSELECTIVE SYNTHESIS; 4-SUBSTITUTED INDOLES; FUNCTIONALIZATION; ALKYNES; OLEFINATION; C-7;
D O I：
10.1002/asia.202001159
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Selective editing of the benzenoid C-H bonds (C4-C7) in indoles/indolines has received great interest because functionalized indoles/indolines are featured in many marketed drugs and natural products. Transition-metal-catalyzed directed C-H functionalization has thus been developed to manipulate the benzenoid core through C-C and C-heteroatom bond formation. This review covers the recent advances in selective C-C bond forming reactions, alkylation, alkenylation and alkynylation, over the benzenoid ring (C4-C7) of indoles/indolines using metal catalysis.
引用
收藏
页码：4184 / 4198
页数：15
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