Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand

被引：21

作者：

Ogawa, Hayato ^{[1
]}

Yamashita, Makoto ^{[1
]}

机构：

[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

来源：

CHEMISTRY LETTERS | 2014年 / 43卷 / 05期

关键词：

FORMING REDUCTIVE ELIMINATION; RH/RU DUAL CATALYST; TANDEM HYDROFORMYLATION/HYDROGENATION; OXIDATIVE ADDITION; PRIMARY ALCOHOLS; BOND; HYDROGENATION; HYDROXIDE; PRODUCE; OLEFIN;

D O I：

10.1246/cl.131208

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mixing of [(PBP)PtCl] complex with 1-decene and H2O afforded isomerized alkenes. Deuterium-labeling experiment indicated the catalytically active hydride species for alkene isomerization formed from water and [(PBP)Pt] complex. Reaction of [(PBP)PtNTf2] with H2O gave a platinum hydride complex having PNNP ligand with a loss of boron atom, but the resulting complex showed low catalytic activity. Two types of cationic platinum hydride complexes were suggested as active species for alkene isomerization.

引用

页码：664 / 666

页数：3

共 2 条

[1] Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene
Ogawa, Hayato
Yamashita, Makoto
DALTON TRANSACTIONS, 2013, 42 (03) : 625 - 629
[2] Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene (vol 42, pg 625, 2013)
Ogawa, Hayato
Yamashita, Makoto
DALTON TRANSACTIONS, 2013, 42 (48) : 16971 - 16971

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