Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand

被引：22

作者：

Ogawa, Hayato ^{[1
]}

Yamashita, Makoto ^{[1
]}

机构：

[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

来源：

CHEMISTRY LETTERS | 2014年 / 43卷 / 05期

关键词：

FORMING REDUCTIVE ELIMINATION; RH/RU DUAL CATALYST; TANDEM HYDROFORMYLATION/HYDROGENATION; OXIDATIVE ADDITION; PRIMARY ALCOHOLS; BOND; HYDROGENATION; HYDROXIDE; PRODUCE; OLEFIN;

D O I：

10.1246/cl.131208

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mixing of [(PBP)PtCl] complex with 1-decene and H2O afforded isomerized alkenes. Deuterium-labeling experiment indicated the catalytically active hydride species for alkene isomerization formed from water and [(PBP)Pt] complex. Reaction of [(PBP)PtNTf2] with H2O gave a platinum hydride complex having PNNP ligand with a loss of boron atom, but the resulting complex showed low catalytic activity. Two types of cationic platinum hydride complexes were suggested as active species for alkene isomerization.

引用

页码：664 / 666

页数：3

共 27 条

[1] Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation-Hydrogenation [J].

Diab, Lisa ;

Smejkal, Tomas ;

Geier, Jens ;

Breit, Bernhard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (43) :8022-8026

[2] Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis [J].

Dong, Guangbin ;

Teo, Peili ;

Wickens, Zachary K. ;

Grubbs, Robert H. .

SCIENCE, 2011, 333 (6049) :1609-1612

[3]

Falbe J., 2009, ULLMANS ENCY IND CHE

[4] Tandem Rhodium-Catalyzed Hydroformylation-Hydrogenation of Alkenes by Employing a Cooperative Ligand System [J].

Fuchs, Daniela ;

Rousseau, Geraldine ;

Diab, Lisa ;

Gellrich, Urs ;

Breit, Bernhard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (09) :2178-2182

[5] CHEMISTS SEEK GREATER RECOGNITION FOR CATALYSIS [J].

HAGGIN, J .

CHEMICAL & ENGINEERING NEWS, 1993, 71 (22) :23-27

[6] Isolation of a PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C?H s Coordination as the Fourth Ligand [J].

Hasegawa, Maki ;

Segawa, Yasutomo ;

Yamashita, Makoto ;

Nozaki, Kyoko .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (28) :6956-6960

[7] Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp2)-OH Bond-Forming Reductive Elimination To Generate Phenol Derivatives [J].

Hayashi, Yumi ;

Wada, Shinji ;

Yamashita, Makoto ;

Nozald, Kyoko .

ORGANOMETALLICS, 2012, 31 (03) :1073-1081

[8] CATALYTIC HYDRATION OF TERMINAL ALKENES TO PRIMARY ALCOHOLS [J].

JENSEN, CM ;

TROGLER, WC .

SCIENCE, 1986, 233 (4768) :1069-1071

[9] Acetaldehyde from Ethylene-A Retrospective on the Discovery of the Wacker Process [J].

Jira, Reinhard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (48) :9034-9037

[10] C-O coupling of LPtIVMe(OH)X complexes in water (X=18OH, OH, OMe; L = di(2-pyridyl)methane sulfonate) [J].

Khusnutdinova, Julia R. ;

Zavalij, Peter Y. ;

Vedernikov, Andrei N. .

ORGANOMETALLICS, 2007, 26 (14) :3466-3483

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