Prediction methods for the critical temperature of n-alkanes

被引：5

作者：

Amorós, J ^{[1
]}

机构：

[1] Univ Cantabria, Dept Fis Aplicada, E-39005 Santander, Spain

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2002年 / 40卷 / 03期

关键词：

critical temperature; melting temperature; alkane; polyethylene;

D O I：

10.1080/0031910021000004856

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The critical temperature of heavy n-alkanes is predicted from the behaviour corresponding to their melting temperature and from several empirical correlations. The prediction methods for the critical temperature of n-alkanes are reviewed, including the new experimental data currently available. The results obtained for T-c(infinity) the limiting value of the critical temperature at n --> infinity, are compared. The calculated and experimental values of T-c coincide in the range n = 5-36 within the actual uncertainties.

引用

页码：269 / 275

页数：7

共 19 条

[1] VAPOR-LIQUID CRITICAL PROPERTIES OF ELEMENTS AND COMPOUNDS .2. NORMAL-ALKANES [J].

AMBROSE, D ;

TSONOPOULOS, C .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (03) :531-546

[2]

ARAKAWA T, 1967, J POLYM SCI C, V16, P653

[3]

BOLOTIN NK, 1991, PHYS LIQUID STATE KI, V19, P75

[4] MELTING TEMPERATURES OF N-PARAFFINS AND CONVERGENCE TEMPERATURE FOR POLYETHYLENE [J].

BROADHURST, MG .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1966, A 70 (06) :481-+

[5] AN ANALYSIS OF SOLID PHASE BEHAVIOR OF NORMAL PARAFFINS [J].

BROADHURST, MG .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1962, 66 (03) :241-+

[6] NEW RELATION FOR PHYSICAL PROPERTIES OF N-ALKANES AND N-ALKYL COMPOUNDS [J].

KREGLEWSKI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (06) :1050-+

[7] THEORY OF NORMAL PARAFFIN LIQUIDS [J].

KURATA, M ;

ISIDA, SI .

JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (06) :1126-1131

[8] Critical properties and vapor pressure equation for alkanes CnH2n+2:: Normal alkanes with n≤36 and isomers for n=4 through n=9 [J].

Lemmon, EW ;

Goodwin, ARH .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2000, 29 (01) :1-39

[9] Vapour-liquid critical temperatures and pressures of normal alkanes with from 19 to 36 carbon atoms, naphthalene and m-terphenyl determined by the pulse-heating technique [J].

Nikitin, ED ;

Pavlov, PA ;

Popov, AP .

FLUID PHASE EQUILIBRIA, 1997, 141 (1-2) :155-164

[10] CRITICAL CONSTANTS OF N-ALKANES WITH FROM 17 TO 24 CARBON-ATOMS [J].

NIKITIN, ED ;

PAVLOV, PA ;

BESSONOVA, NV .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (02) :177-182

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