Combustion. synthesis and luminescence properties of nanocrystalline monoclinic SrAl2O4:Eu2+

被引：69

作者：

Fu, ZL ^{[1
]}

Zhou, SH ^{[1
]}

Yu, YN ^{[1
]}

Zhang, SY ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 395卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.07.114

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanocrystals of SrAl2O4:Eu2+ have been prepared by combustion synthesis. The results of XRD indicated that the resulting SrAl2O4:Eu2+ nanocrystals have a reduced and distorted monoclinic lattice compared with bulk materials. Both the excitation and emission spectra of SrAl2O4:Eu2+ nanocrystals shifts to higher energies in contrast to the bulk materials. The band structure calculation is performed using first-principles full potential-linearized augmented plane wave method within density functional theory. The calculated results are in reasonable agreement with our experimental results. (C) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：285 / 289

页数：5

相关论文

共 11 条

[1] OPTICAL AND ELECTRICAL PROPERTIES OF SRAL2O4-EU2+ [J].

ABBRUSCATO, V .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1971, 118 (06) :930-+

[2] Sol-gel synthesis and the effect of boron addition on the phosphorescent properties of SrAl2O4:Eu2+,Dy3+ phosphors [J].

Chen, IC ;

Chen, TM .

JOURNAL OF MATERIALS RESEARCH, 2001, 16 (03) :644-651

[3] New long phosphorescent phosphor with high brightness, SrAl2O4:Eu2+,Dy3+ [J].

Matsuzawa, T ;

Aoki, Y ;

Takeuchi, N ;

Murayama, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (08) :2670-2673

[4] FLUORESCENT PROPERTIES OF ALKALINE EARTH ALUMINATES OF TYPE MAL204 ACTIVATED BY DIVALENT EURROPIUM [J].

PALILLA, FC ;

LEVINE, AK ;

TOMKUS, MR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1968, 115 (06) :642-&

[5]

Perdew JP, 1997, PHYS REV LETT, V78, P1396, DOI 10.1103/PhysRevLett.77.3865

[6] LUMINESCENCE OF EU2+ IN BARIUM AND STRONTIUM ALUMINATE AND GALLATE [J].

POORT, SHM ;

BLOKPOEL, WP ;

BLASSE, G .

CHEMISTRY OF MATERIALS, 1995, 7 (08) :1547-1551

[7] COMPOUND FORMATION MEO-M2O3 .4. STRUCTURE OF MONOCLINIC SRAL2O4 [J].

SCHULZE, AR ;

MULLERBUSCHBAUM, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 475 (04) :205-210

[8] First-principles simulation: ideas, illustrations and the CASTEP code [J].

Segall, MD ;

Lindan, PJD ;

Probert, MJ ;

Pickard, CJ ;

Hasnip, PJ ;

Clark, SJ ;

Payne, MC .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (11) :2717-2744

[9] SOFT SELF-CONSISTENT PSEUDOPOTENTIALS IN A GENERALIZED EIGENVALUE FORMALISM [J].

VANDERBILT, D .

PHYSICAL REVIEW B, 1990, 41 (11) :7892-7895

[10] Size-dependent chromaticity in YBO3:Eu nanocrystals:: Correlation with microstructure and site symmetry [J].

Wei, ZG ;

Sun, LD ;

Liao, CS ;

Yin, JL ;

Jiang, XC ;

Yan, CH ;

Lü, SZ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (41) :10610-10617