Structure of boron nitride nanoscale cones:: Ordered stacking of 240° and 300° disclinations

被引:109
作者
Bourgeois, L [1 ]
Bando, Y [1 ]
Han, WQ [1 ]
Sato, T [1 ]
机构
[1] Natl Inst Res Inorgan Mat, Tsukuba, Ibaraki 3050044, Japan
关键词
D O I
10.1103/PhysRevB.61.7686
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Recently discovered boron nitride (BN) nanoscale cone particles are shown to consist of an ordered stacking of seamless conical shells. High-resolution transmission electron microscopy and nanobeam electron diffraction allowed the orientation of the BN hexagonal rings to be determined. In all but one case, the results conformed with a model of orderly stacked 240 degrees disclinations, which is the smallest cone geometry ensuring the presence of B-N bonds only. One case of a nanoscale cone constituted of 300 degrees disclinations was found, implying that structures containing line defects of non-B-N bonds may form.
引用
收藏
页码:7686 / 7691
页数:6
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