Hydrosilylation of alkenes with early main-group metal catalysts

被引：185

作者：

Buch, F ^{[1
]}

Brettar, H ^{[1
]}

Harder, S ^{[1
]}

机构：

[1] Univ Duisburg Gesamthsch, D-45117 Essen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 17期

关键词：

alkaline-earth metals; homogeneous catalysis; hydrides; hydrosilylation; silanides;

D O I：

10.1002/anie.200504164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Clean conversion of conjugated alkenes with exclusive formation of one regioisomer is achieved by using a new class of hydrosilylation catalysts based on early main-group metals (Ca, Sr, and K). The regioselectivity can be switched to the other isomer through the choice of the metal and solvent polarity. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2741 / 2745

页数：5

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