Elaboration, Electrochemical Investigation and Morphological Study of the Coating Behavior of a New Polymeric Polyepoxide Architecture: Crosslinked and Hybrid Decaglycidyl of Phosphorus Penta Methylene Dianiline on E24 Carbon Steel in 3.5% NaCl

被引:60
作者
Hssissou, Rachid [1 ]
Benzidia, Bouchra [2 ]
Hajjaji, Najat [2 ]
Elharfi, Ahmed [1 ]
机构
[1] Ibn Tofail Univ, Dept Chem, Fac Sci, LAPPE,TOCP, POB 133, Kenitra 14000, Morocco
[2] Ibn Tofail Univ, Fac Sci, Dept Chem, Lab Mat Electrochem & Environm,Team Corros,Protec, POB 133, Kenitra 14000, Morocco
关键词
DGPMDAP; architecture; coating; crosslinking; formulation; carbon steel; electrochemical studies; EPOXY-RESIN; ELECTROPOLYMERIZATION; PYRROLE;
D O I
10.4152/pea.201903179
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We developed and applied in our work a new polyepoxide polymer, decaglycidyl phosphorus penta methylene dianiline, to study its coating behavior in a marine environment. Then, we tested the new crosslinked and formulated macromolecular binder (DGPMDAP), which is used as an anticorrosive coating on E24 carbon steel, in 3.5% NaCl. So as to evaluate and examine the DGPMDAP coating performance in the field of E24 carbon steel corrosion, we applied the different E-1 (DGPMDAP/MDA) and E-2 (DGPMDAP/MDA/PN) formulations on the metal substrate. The stationary and transient electrochemical studies are very interesting; and, in order to confirm the obtained results, we dispersed the charge of the natural phosphate that was incorporated in the E-2 (DGPMDAP/MDA/PN) macromolecular matrix, through the use of a polarizing optical microscope.
引用
收藏
页码:179 / 191
页数:13
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