A Novel Green Synthesis of Silver Nanoparticles Using Gum Karaya: Characterization, Antimicrobial and Catalytic Activity Studies

被引:57
|
作者
Venkatesham, Maragoni [1 ]
Ayodhya, Dasari [1 ]
Madhusudhan, Alle [1 ]
Kumari, Amrutham Santoshi [1 ]
Veerabhadram, Guttena [1 ]
Mangatayaru, Kotu Girija [2 ]
机构
[1] Osmania Univ, Dept Chem, Hyderabad 500007, Andhra Pradesh, India
[2] Palamuru Univ, Dept Chem, Mahabubnagar, India
关键词
Autoclave; Gum karaya; Silver nanoparticles; Microbial activity; 4-Nitrophenol; Pseudo first order reaction; CHEMICAL-REDUCTION METHOD; NANOSILVER; RELEASE; SURFACE; GOLD;
D O I
10.1007/s10876-013-0620-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Stable silver nanoparticles have been synthesized using gum karaya acting as both reducing and stabilizing agent without using any synthetic reagent. The reaction is performed using water, which is an environmentally safe solvent. This reaction was carried out in an autoclave at a pressure of 15 psi and 120 A degrees C temperature by varying the time. The influence of different parameters such as time, change of concentration of silver nitrate and concentration of gum karaya on the formation of silver nanoparticles has been studied. The synthesized silver nanoparticles are characterized by UV-Vis spectroscopy, FTIR, XRD and TEM. UV-Vis analysis of the sample confirmed the formation of silver nanoparticles exhibiting a sharp peak at a wavelength of 420 nm. TEM micrographs showed the formation of well-dispersed silver nanoparticles of size 2-4 nm. The antimicrobial activity of silver nanoparticles stabilized in gum karaya is tested against Escherichia coli, Micrococcus luteus and is found to be possessing inhibiting property. The silver nanoparticles stabilized in gum karaya exhibited very good catalytic activity and the kinetics of the reaction was found to be pseudo first order with respect to the 4-nitrophenol.
引用
收藏
页码:409 / 422
页数:14
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