SnCl4-organic base:: Highly efficient catalyst system for coupling reaction of CO2 and epoxides

被引：56
作者：
Jing, Huanwang
Nguyen, SonBinh T.
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
[2] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 261卷 / 01期
关键词：
carbon dioxide; epoxides; organic base; stannic chloride; coupling reaction;
D O I：
10.1016/j.molcata.2006.07.057
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A simple and highly efficient catalyst system of SnCl4-organic base was developed to catalyze the coupling reaction of carbon dioxide and epoxides in very mild condition to yield the cyclic carbonates. The proposed mechanism was described in terms of in situ Sn-119 NMR investigations. (c) 2006 Elsevier B.V. All rights reserved.
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页码：12 / 15
页数：4
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