Selection of new absorbents for carbon dioxide capture

被引:273
作者
Ma'mun, Sholeh
Svendsen, Hallvard F. [1 ]
Hoff, Karl A.
Juliussen, Olav
机构
[1] Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway
[2] SINTEF, N-7465 Trondheim, Norway
关键词
carbon dioxide; absorption; absorbent selection; alkanolamines; equilibrium; cyclic capacity;
D O I
10.1016/j.enconman.2006.04.007
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work focuses on selecting new absorbents for CO2 capture. Absorption of CO2 was studied at 40 degrees C using both single and mixed amine-based absorbents. The experimental results show that most absorbents tested have a poorer performance than MEA, but that aqueous AEEA might be a possible contender. In addition to the absorption measurements, the VLE of CO2 in the selected absorbent, the aqueous 2.9 M AEEA, were studied at 40 and 120 degrees C. The equilibrium partial pressures of CO2 in the aqueous 2.9 M AEEA at the temperature of removal (40 degrees C) and that of regeneration (120 degrees C) are lower than for aqueous 5.0 M MEA, but the maximum net cyclic capacity is somewhat higher. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:251 / 258
页数:8
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