Resonant Raman study of the structure and electronic properties of single-wall carbon nanotubes

被引：228
作者：
Alvarez, L
Righi, A
Guillard, T
Rols, S
Anglaret, E [1 ]
Laplaze, D
Sauvajol, JL
机构：
[1] Univ Montpellier 2, CNRS, UMR 5581, Dynam Phases Condensees Grp, F-34095 Montpellier 5, France
[2] CNRS, UPR 8521, IMP Odeillo, F-66125 Font Romeu, France
[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
来源：
CHEMICAL PHYSICS LETTERS | 2000年 / 316卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(99)01291-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We investigate the laser-energy dependence of the Raman profile of single-wall carbon nanotube (SWNT) samples with various distributions of diameters. We show that resonant Raman is an efficient tool for the study of the structure and electronic properties of SWNT. The tube diameter distribution is derived from the comparison between the experimental frequencies of the radial A(1g) breathing mode range (RBM) and the calculated RBM frequency of SWNT bundles. Metallic or semi-conducting tubes are identified in the light of calculations of allowed optical transitions. The assignments are confirmed by the observation (absence) of a Breit-Wigner-Fano-like lineshape for the tangential graphite-like modes of metallic (semiconducting) nanotubes. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：186 / 190
页数：5
相关论文
共 16 条
[1]   Raman characterization of single wall carbon nanotubes prepared by the solar energy route [J].
Anglaret, E ;
Bendiab, N ;
Guillard, T ;
Journet, C ;
Flamant, G ;
Laplaze, D ;
Bernier, P ;
Sauvajol, JL .
CARBON, 1998, 36 (12) :1815-1820
[2]   Effect of the growth temperature on the diameter distribution and chirality of single-wall carbon nanotubes [J].
Bandow, S ;
Asaka, S ;
Saito, Y ;
Rao, AM ;
Grigorian, L ;
Richter, E ;
Eklund, PC .
PHYSICAL REVIEW LETTERS, 1998, 80 (17) :3779-3782
[3]   Production of carbon nanotubes by the solar route [J].
Guillard, T ;
Cetout, S ;
Alvarez, L ;
Sauvajol, JL ;
Anglaret, E ;
Bernier, P ;
Flamant, G ;
Laplaze, D .
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 1999, 5 (03) :251-256
[4]   Evidence for size-dependent discrete dispersions in single-wall nanotubes [J].
Kasuya, A ;
Sasaki, Y ;
Saito, Y ;
Tohji, K ;
Nishina, Y .
PHYSICAL REVIEW LETTERS, 1997, 78 (23) :4434-4437
[5]   Optical properties of single-wall carbon nanotubes [J].
Kataura, H ;
Kumazawa, Y ;
Maniwa, Y ;
Umezu, I ;
Suzuki, S ;
Ohtsuka, Y ;
Achiba, Y .
SYNTHETIC METALS, 1999, 103 (1-3) :2555-2558
[6]   Raman modes of metallic carbon nanotubes [J].
Pimenta, MA ;
Marucci, A ;
Empedocles, SA ;
Bawendi, MG ;
Hanlon, EB ;
Rao, AM ;
Eklund, PC ;
Smalley, RE ;
Dresselhaus, G ;
Dresselhaus, MS .
PHYSICAL REVIEW B, 1998, 58 (24) :16016-16019
[7]   Diameter-selective Raman scattering from vibrational modes in carbon nanotubes [J].
Rao, AM ;
Richter, E ;
Bandow, S ;
Chase, B ;
Eklund, PC ;
Williams, KA ;
Fang, S ;
Subbaswamy, KR ;
Menon, M ;
Thess, A ;
Smalley, RE ;
Dresselhaus, G ;
Dresselhaus, MS .
SCIENCE, 1997, 275 (5297) :187-191
[8]   Theory of size-dependent resonance Raman scattering from carbon nanotubes [J].
Richter, E ;
Subbaswamy, KR .
PHYSICAL REVIEW LETTERS, 1997, 79 (14) :2738-2741
[9]   Diffraction by finite-size crystalline bundles of single wall nanotubes [J].
Rols, S ;
Almairac, R ;
Henrard, L ;
Anglaret, E ;
Sauvajol, JL .
EUROPEAN PHYSICAL JOURNAL B, 1999, 10 (02) :263-270
[10]  
ROLS S, IN PRESS
12