Synthesis and crystal structure of cis-dioxomolybdenum(VI) complex with salicylaldehyde-2-pyrazinoylhydrazone

被引：0

作者：

Sanyal, GS ^{[1
]}

Ganguly, R

Nath, PK

Butcher, RJ

机构：

[1] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India

[2] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2002年 / 79卷 / 06期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MoO2Cl2(DMF)(2) reacts with salic ylaldehyde-2-pyrazinoylhydrazone (SAPH) in methanol to afford the title complex. X-Ray structure analysis reveals that the complex possesses the usual cis-MoO22+ moiety and SAPH behaves as a dianionic tridentate donor coordinating through azomethine nitrogen, enolic and phenolic oxygens. The sixth coordination site around Mo is occupied by a water molecule in the distorted octahedral geometry of the complex. The second water molecule is present as water of crystallization.

引用

页码：486 / 488

页数：3

共 13 条

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