In situ preparation, structure, fluorescence and TDDFT calculations of [(CdCl3)2(μ2-HCl)]2[CdCl4(HCl)][N,N′-dimethyl-4,4′-bipyridinium]3

被引：0
|
作者：
Chen, Wen-Tong [1 ,2 ]
Hu, Rong-Hua [1 ]
Luo, Zhi-Gang [1 ]
Chen, Hua-Long [1 ]
Zhang, Xian [1 ]
Liu, Juan [2 ]
机构：
[1] Jinggangshan Univ, Inst Appl Chem, Sch Chem & Chem Engn, Jiangxi Prov Key Lab Coordinat Chem, Jian 343009, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2014年 / 53卷 / 03期
关键词：
COORDINATION POLYMERS; CHLORIDE;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel cadmium-4,4'-bipyridinium compound, [(CdCl3)(2)(mu 2HCl)](2)[CdCl4(HCl)][N,N'-dimethyl-4,4'-bipyridinium](3) (1) in which the N,N'-dimethyl-4,4'-bipyridinium moiety is obtained in situ, has been synthesized via a solvothermal reaction and characterized by X-ray diffraction analyses. Compound (1) crystallizes in the P31c space group of rhombohedral system. The [(CdCl3)(2)(mu(2)-HCl)](2-) anion, [CdCl4(HCl)](2-) anion and [N,N'-dimethyl-4,4'-bipyridinium](2+) cation are interlinked through hydrogen bonding interactions to yield a three-dimensional supramolecular network Fluorescence investigation reveals that compound (1) displays an intensive emission band in the green region. In combination with the theoretical studies, it may be concluded that the emission band originates mainly from the ligand-to-ligand charge-transfer transition, accompanied by a minor metal-to-ligand charge-transfer (MLCT) transition.
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页码：294 / 298
页数：5
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