Robust and reusable supported palladium catalysts for cross-coupling reactions in flow

被引：42

作者：

Reynolds, William R. ^{[1
,2
]}

Plucinski, Pawel ^{[2
,3
]}

Frost, Christopher G. ^{[1
,2
]}

机构：

[1] Univ Bath, Ctr Sustainable Chem Technol, Bath BA2 7AY, Avon, England

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] Univ Bath, Dept Chem Engn, Bath BA2 7AY, Avon, England

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

ORGANIC-SYNTHESIS; BATCH; NANOPARTICLES;

D O I：

10.1039/c3cy00836c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two novel polymer encapsulated silica supported palladium catalysts have been prepared and shown to be highly active, robust and recyclable catalysts for Heck and Suzuki-Miyaura cross coupling reactions under continuous flow conditions. They were demonstrated to give excellent conversions of both electron rich and electron deficient substrates and the catalysts were used for over 50 hours continuous operation without any appreciable decrease in catalytic activity and low levels of Pd leaching measured by ICP-MS.

引用

页码：948 / 954

页数：7

共 50 条

[21] A simple and efficient reusable polystyrene-supported palladium catalyst for Hiyama cross-coupling
Diebold, Carine
Derible, Antoine
Becht, Jean-Michel
Le Drian, Claude
TETRAHEDRON, 2013, 69 (01) : 264 - 267
[22] Palladium Nanoparticles Supported on Porous Silica Materials as Heterogeneous Catalysts of C-C Coupling and Cross-Coupling Reactions
Mastalir, Agnes
Molnar, Arpad
CHEMCATCHEM, 2023, 15 (19)
[23] Heterogeneous Suzuki cross-coupling reactions over palladium/hydrotalcite catalysts
Mora, Manuel
Jimenez-Sanchidrian, Cesar
Ruiz, J. Rafael
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 302 (02) : 568 - 575
[24] Use of palladium-phosphinous acid catalysts in cross-coupling reactions
Lerebours, Rachel
Wolf, Christian
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3199 - U3199
[25] HIGHLY SELECTIVE GRIGNARD CROSS-COUPLING REACTIONS BY NICKEL AND PALLADIUM CATALYSTS
KUMADA, M
HAYASHI, T
TAMAO, K
KONISHI, M
MINATO, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 183 (MAR): : 72 - INOR
[26] Silica-supported terpyridine palladium(II) complex as an efficient and reusable catalyst for Heck and Suzuki cross-coupling reactions
Amini, Mostafa M.
Feiz, Afsaneh
Dabiri, Minoo
Bazgir, Ayoob
APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (02) : 86 - 90
[27] Palladium nanoparticles supported on polymer: An efficient and reusable heterogeneous catalyst for the Suzuki cross-coupling reactions and aerobic oxidation of alcohols
Karami, Kazem
Ghasemi, Mahdiyeh
Naeini, Nasrin Haghighat
CATALYSIS COMMUNICATIONS, 2013, 38 : 10 - 15
[28] Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts
Shimizu, Ken-ichi
Shimura, Katsuya
Ohshima, Keiichiro
Tamura, Masazumi
Satsuma, Atsushi
GREEN CHEMISTRY, 2011, 13 (11) : 3096 - 3100
[29] Immobilization strategies for surface-supported molecular palladium cross-coupling catalysts
Marquard, Angela
Goldsmith, Randall
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[30] Carbon-supported Palladium and Ruthenium Nanoparticles: Application as Catalysts in Alcohol Oxidation, Cross-coupling and Hydrogenation Reactions
Garcia-Suarez, Eduardo J.
Lara, Patricia
Garcia, Ana B.
Philippot, Karine
RECENT PATENTS ON NANOTECHNOLOGY, 2013, 7 (03) : 247 - 264

← 1 2 3 4 5 →