ZINC HALIDE COMPLEXES OF THIONICOTINAMIDE; CRYSTAL STRUCTURE OF DICHLORIDO BIS(THIONICOTINAMIDE-κN)ZINC(II)

被引：1

作者：

Akhtar, M. ^{[1
]}

Malik, M. R. ^{[1
]}

Tahir, M. N. ^{[2
]}

Nadeem, S. ^{[1
]}

Altaf, M.

Sohail, M.

Ali, S. ^{[1
]}

Ahmad, S. ^{[3
]}

机构：

[1] Quaid I Azam Univ, Dept Chem, Islamabad, Pakistan

[2] Univ Sargodha, Dept Phys, Sargodha, Pakistan

[3] Prince Sattam bin Abdulaziz Univ, Dept Chem, Coll Sci & Humanities, Al Kharj, Saudi Arabia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 01期

关键词：

zinc(II); thionicotinamide; NMR spectroscopy; crystal structure; METAL-IONS; COORDINATION CHEMISTRY; LIGANDS; DERIVATIVES; CYSTEAMINE; FEATURES; CADMIUM; COPPER; HG;

D O I：

10.1134/S0022476617010243

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc halide complexes of thionicotinamide (TNA) having the general formula [Zn(TNA)(2)X-2] (X = Cl-, Br-, I-) are prepared and characterized by thermal analysis, IR and NMR spectroscopy. The crystal structure of one of them, dichloridobis(thionicotinamide-kappa N) zinc(II), [Zn(TNA)(2)Cl-2] (1), is determined using X-ray crystallography. In 1, the zinc atom is coordinated by two thionicotinamide ligands through nitrogen atoms and two chloride ions in a distorted tetrahedral coordination environment. The molecular structure of the complex is stabilized through intermolecular hydrogen bonding.

引用

页码：178 / 182

页数：5

共 50 条

[41] Zinc(II)-pyridylthioazophenol system: synthesis, characterization and crystal structure
Dhara, Pulak K.
Drew, Michael G. B.
Chattopadhyay, Pabitra
JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (06) : 627 - 634
[42] Crystal structure of dichlorido(2,2 ':6 ',2 ''-terpyridine-kappa N-3,N ',N '')zinc: a redetermination
Kong, Cheng-Cheng
Zhou, Jia Zheng
Yu, Jian-Hua
Li, Sheng-Li
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M382 - +
[43] Composition and thermal stability of bis(dipyrrolylmethenato)zinc(II) crystal solvates with N,N-dimethylformamide
Guseva, G. B.
Antina, E. V.
Ksenofontov, A. A.
Barannikov, V. P.
Vyugin, A. I.
THERMOCHIMICA ACTA, 2014, 589 : 31 - 36
[44] Synthesis and Spectral Studies on N,N,N′,N′-Tetramethylethy-lenediamine Adducts of Bis(4-methylpiperidinecarbodithioato-S,S′)M(II) (M = zinc, cadmium): Single Crystal X-Ray Structure of Bis(4-methylpiperidinecarbodithioato-S,S′) (N,N,N′,N′-Tetramethylethylenediamine)zinc(II)
Srinivasan, N.
Thirumaran, S.
Kohli, Sabeta
Rajnikant
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (06) : 505 - 509
[45] N,N-Di(4-pyridyl)animomethylferrocene Zinc(II) and Cadmium(II) complexes: Synthesis, crystal structures and electrochemistry
Lu, Jiangfeng
Zhang, Ning
Zhu, Xiaowei
Sun, Qiaozhen
Zhang, Bingguang
Liu, Hao
Zhao, Bo
INORGANIC CHEMISTRY COMMUNICATIONS, 2019, 103 : 53 - 56
[46] Crystal structure and thermal behaviour of copper(II) and zinc(II) complexes with N-pyrrolidine-N′-(2-chloro-benzoyl)thiourea
Arslan, H
Flörke, U
Külcü, N
Emen, MF
JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (02) : 223 - 228
[47] Zinc(II) halide complexes with 2-methoxyaniline ligand: Synthesis, characterization, thermal analyses, crystal structure determination and luminescent properties
Amani, Vahid
JOURNAL OF MOLECULAR STRUCTURE, 2018, 1155 : 477 - 483
[48] Syntheses, crystal structures and luminescence of zinc(II) and cadmium(II) complexes with 4′-substituted 2,2′:6′,2"-terpyridines
Fu, Wei-Wei
Zhang, Fu-Xing
Kuang, Dai-Zhi
Liu, Yang
Yang, Ying-Qun
JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (07) : 1177 - 1188
[49] Crystal structure of bis(isonicotinamide-kappa N-1)bis(thiocyanato-kappa N)zinc
Neumann, Tristan
Jess, Inke
Naether, Christian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 922 - +
[50] Zinc(II) and Co(II) complexes based on bis(N-allylbenzimidazol-2-ylmethyl) aniline: synthesis, crystal structures and antioxidative activity
Wu, Huilu
Zhang, Han
Wang, Fei
Peng, Hongping
Cui, Yiming
Li, Yuanyuan
Zhang, Yanhui
JOURNAL OF CHEMICAL RESEARCH, 2015, (02) : 76 - 81

← 1 2 3 4 5 →