ZINC HALIDE COMPLEXES OF THIONICOTINAMIDE; CRYSTAL STRUCTURE OF DICHLORIDO BIS(THIONICOTINAMIDE-κN)ZINC(II)

被引：1

作者：

Akhtar, M. ^{[1
]}

Malik, M. R. ^{[1
]}

Tahir, M. N. ^{[2
]}

Nadeem, S. ^{[1
]}

Altaf, M.

Sohail, M.

Ali, S. ^{[1
]}

Ahmad, S. ^{[3
]}

机构：

[1] Quaid I Azam Univ, Dept Chem, Islamabad, Pakistan

[2] Univ Sargodha, Dept Phys, Sargodha, Pakistan

[3] Prince Sattam bin Abdulaziz Univ, Dept Chem, Coll Sci & Humanities, Al Kharj, Saudi Arabia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 01期

关键词：

zinc(II); thionicotinamide; NMR spectroscopy; crystal structure; METAL-IONS; COORDINATION CHEMISTRY; LIGANDS; DERIVATIVES; CYSTEAMINE; FEATURES; CADMIUM; COPPER; HG;

D O I：

10.1134/S0022476617010243

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc halide complexes of thionicotinamide (TNA) having the general formula [Zn(TNA)(2)X-2] (X = Cl-, Br-, I-) are prepared and characterized by thermal analysis, IR and NMR spectroscopy. The crystal structure of one of them, dichloridobis(thionicotinamide-kappa N) zinc(II), [Zn(TNA)(2)Cl-2] (1), is determined using X-ray crystallography. In 1, the zinc atom is coordinated by two thionicotinamide ligands through nitrogen atoms and two chloride ions in a distorted tetrahedral coordination environment. The molecular structure of the complex is stabilized through intermolecular hydrogen bonding.

引用

页码：178 / 182

页数：5

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