Synthesis, characterization, and catalytic behavior of ruthenium(II) Schiff base complexes

被引：48
作者：
Serron, SA
Haar, CM
Nolan, SP
Brammer, L
机构：
[1] UNIV NEW ORLEANS,DEPT CHEM,NEW ORLEANS,LA 70148
[2] UNIV MISSOURI,DEPT CHEM,ST LOUIS,MO 63121
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 23期
关键词：
D O I：
10.1021/om970600f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes (X-6-acen)Ru(PPh3)(2) (X = H (1) and F (2)) have been prepared and characterized by standard spectroscopic and analytical methods. Additionally, the solid-state structure of 2 has been determined by single-crystal X-ray diffraction. Ligand exchange reactions involving the labile Ru-PPh3 bond are easily performed, and complex 1 serves as a catalyst precursor for the isomerization of 1-hexene.
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页码：5120 / 5123
页数：4
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