Nitric acid in the presence of supported P2O5 on silica gel affords an efficient and mild system for oxidation of organic compounds under solvent-free conditions

被引：2
|
作者：
Hajipour, Abdol R. [1 ]
Guo, Lian-Wang
Ruolho, Arnold E.
机构：
[1] Isfahan Univ Technol, Pharmaceut Res Lab, Coll Chem, Esfahan, Iran
[2] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI USA
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2006年 / 456卷
关键词：
is oxidation; nitric acid; solvent-free; sulfoxide;
D O I：
10.1080/15421400600786363
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This paper describes an efficient and easy method for oxidation of alcohols 1 and sulfides 2 to their corresponding carbonyl compounds 3 and sulfoxides 4 with nitric acid in the presence of supported P2O5 on silica gel under solvent-free conditions in high yields.
引用
收藏
页码：85 / 93
页数：9
相关论文
共 50 条
  • [21] Heteropoly Acid Supported on Silica Gel as Catalyst for the Asymmetric Transfer Allylation of Aromatic Aldehydes under Solvent-Free Conditions
    Nunokawa, Shiori
    Oki, Kazuya
    Yamashita, Keisuke
    Okuyama, Atsushi
    Ueda, Tadaharu
    Nakano, Keiji
    Ichikawa, Yoshiyasu
    Kotsuki, Hiyoshizo
    SYNLETT, 2017, 28 (05) : 597 - 600
  • [22] P2O5/SiO2 as a New, Efficient and Reusable Catalyst for Preparation of 4,4′-Epoxydicoumarins Under Solvent-free Conditions
    Wu, Liqiang
    Wang, Xiao
    E-JOURNAL OF CHEMISTRY, 2011, 8 (04) : 1626 - 1631
  • [23] Selective monotetrahydropyranylation of symmetrical diols using P2O5/SiO2 under solvent-free conditions and their depyranylation
    Eshghi, Hossein
    Rahimizadeh, Mohammad
    Saberi, Sattar
    CHINESE CHEMICAL LETTERS, 2008, 19 (09) : 1063 - 1067
  • [24] P2O5/SiO2 as catalyst for the preparation of 1,1-diacetates under solvent-free conditions
    Eshghi, H
    Gordi, Z
    Khanlarkhani, A
    IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY, 2004, 28 (A1): : 145 - 148
  • [25] P2O5/Al2O3 as an efficient heterogeneous catalyst for chemoselective synthesis of 1,1-diacetates under solvent-free conditions
    Hajipour, Abdol R.
    Zarei, Amin
    Ruoho, Arnold E.
    TETRAHEDRON LETTERS, 2007, 48 (16) : 2881 - 2884
  • [26] Highly efficient, mild and chemo- and stereoselective synthesis of enaminones and enamino esters using silica supported perchloric acid under solvent-free conditions
    Das, B
    Venkateswarlu, K
    Majhi, A
    Reddy, MR
    Reddy, KN
    Rao, YK
    Ravikumar, K
    Sridhar, B
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 246 (1-2) : 276 - 281
  • [27] A convenient and efficient synthesis of N-acylsulfonamides in the presence of silica phosphoric acid under heterogeneous and solvent-free conditions
    Massah, Ahmad Reza
    Dabagh, Mina
    Afshar, Maryam
    Momeni, Ahmad Reza
    Aliyan, Hamid
    Naghash, Hamid Javaherian
    TURKISH JOURNAL OF CHEMISTRY, 2007, 31 (06) : 611 - 616
  • [28] Supported bismuth(III) nitrate on silica sulfuric acid as useful reagent for nitration of aromatic compounds under solvent-free conditions
    Hajipour, AR
    Zarei, A
    Ruoho, AE
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 41 (10) : 1493 - 1495
  • [29] Supported Bismuth(III) Nitrate on Silica Sulfuric Acid as Useful Reagent for Nitration of Aromatic Compounds under Solvent-Free Conditions
    A. R. Hajipour
    A. Zarei
    A. E. Ruoho
    Russian Journal of Organic Chemistry, 2005, 41 : 1493 - 1495
  • [30] Phosphorus pentoxide supported on silica gel and alumina (P2O5/SiO2, P2O5/Al2O3) as useful catalysts in organic synthesis
    Eshghi, Hossein
    Hassankhani, Asadollah
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2012, 9 (04) : 467 - 482
12345