Metal complexes of biologically important ligands, CXLVI.: Bis(allyl)-N,O-α-aminocarboxylate-rhodium complexes

被引：4
|
作者：
Ponikwar, W [1 ]
Mayer, P [1 ]
Beck, W [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2002年 / 57卷 / 07期
关键词：
D O I：
10.1515/znb-2002-0714
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of [(eta(3)-C3H5)(2)Rh-mu-Cl](2) with the anions of alpha-amino acids (glycine, L-alanine, L-valine, L-isoleucine, L-proline, L-phenylalanine, L-phenylglycine, L-thyrosine) afford the NO-chelates (eta(3)-C3H5)(2)Rh(alpha-amino carboxylate). For complex (eta(3)-C3H5)(2)Rh(glycinate) dynamic behaviour in solution could be observed by H-1 NMR. The structure of (eta(3)-C3H5)(2)Rh(L-prolinate) was determined by X-ray diffraction.
引用
收藏
页码：810 / 818
页数：9
相关论文
共 50 条
  • [1] Metal complexes of biologically important ligands, CXXXII.: α-Aminocarboxylate chelates of cyclometalated rhodium complexes
    Böhm, A
    Polborn, K
    Beck, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2001, 56 (03): : 293 - 296
  • [2] Metal complexes of biologically important ligands, CXXXIII [1]. α-aminocarboxylate chelates of cyclometalated rhodium complexes
    Böhm, Andreas
    Polborn, Kurt
    Beck, Wolfgang
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2001, 56 (03): : 293 - 296
  • [3] Metal complexes of biologically important ligands. CLXIII - N,O-chelate complexes with propargylglycinate
    Ponikwar, Walter
    Hauck, Thomas
    Beck, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (12-13): : 1983 - 1985
  • [4] Metal complexes of biologically important ligands.: CXXIII.: Isophthaloyl and terephthaloyl-di[β,γ,δ)-amino-α-aminocarboxylate] bridged dinuclear ruthenium, rhodium and iridium halfsandwich complexes
    Chen, JT
    Sünkel, K
    Beck, W
    JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG, 1999, 341 (08): : 792 - 796
  • [5] Metal complexes of biologically important ligands, CVI. Metal complexes of donor substituted oxazolones and of bis(oxazolones)
    Prem, M
    Bauer, W
    Polborn, K
    Beck, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1998, 53 (09): : 965 - 972
  • [6] METAL-COMPLEXES WITH BIOLOGICALLY IMPORTANT LIGANDS .22. DICARBONYL RHODIUM(I) COMPLEXES WITH NUCLEOBASES AND NUCLEOSIDES
    SINGH, MM
    ROSOPULOS, Y
    BECK, W
    CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (04): : 1364 - 1369
  • [7] Metal complexes of biologically important ligands, CXXXI *. Pentamethylcyclopentadienyl halfsandwich complexes of rhodium and iridium with glycosyl-α-iminocarboxylates as chelate ligands
    Krawielitzki, Stefan
    Beck, Wolfgang
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2001, 56 (01): : 62 - 68
  • [8] Metal complexes of biologically important ligands, CIL.: Organometallic η2-N,O-lysinato-complexes
    Ponikwar, W
    Beck, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2003, 58 (01): : 92 - 96
  • [9] Metal complexes of biologically important ligands, CXXXI.: Pentamethylcyclopentadienyl halfsandwich complexes of rhodium and iridium with glycosyl-α-iminocarboxylates as chelate ligands
    Krawielitzki, S
    Beck, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2001, 56 (01): : 62 - 68
  • [10] Metal complexes of biologically important ligands, part CLXIV -: Aryl phosphine nickel(II) and palladium(II) complexes with N,O-amino-carboxylate chelate ligands [(Aryl)(R3P)M(N,O-α-aminocarboxylate)] (M = Ni, Pd).: Catalysts for the polymerization of olefins
    Ponikwar, Walter
    Mihan, Shahrarn
    Suenkel, Karlheinz
    Beck, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (14): : 2299 - 2304
12345