Biomass-derived solvents as effective media for cross-coupling reactions and C-H functionalization processes

被引：159
|
作者：
Santoro, Stefano [1 ]
Ferlin, Francesco [1 ]
Luciani, Lorenzo [1 ]
Ackermann, Lutz [2 ]
Vaccaro, Luigi [1 ]
机构：
[1] Univ Perugia, Dipartimento Chim Biol & Biotecnol, Lab Green Synthet Organ Chem, Via Elce Sotto 8, I-06123 Perugia, Italy
[2] Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany
来源：
GREEN CHEMISTRY | 2017年 / 19卷 / 07期
关键词：
CATALYZED DIRECT ARYLATION; LIFE-CYCLE INVENTORY; UREA-SALT MIXTURES; BIO-BASED SOLVENTS; GAMMA-VALEROLACTONE; GREEN SOLVENT; ETHYL LACTATE; BOND ACTIVATION; DIRECTING GROUP; LEVULINIC ACID;
D O I：
10.1039/c7gc00067g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium-catalyzed cross-coupling reactions are indispensable tools in molecular syntheses with numerous applications in academia and for the practitioners in the chemical and pharmaceutical industries. Recent years have witnessed the increasing use of biomass-derived solvents as green reaction media in the palladium-, copper-and nickel-catalyzed cross-coupling technology, the key advances until January 2017 being summarized in this review. In addition, very recent first examples of transition metal-catalyzed C-H activations in biomass-originated solvents, such as gamma-valerolactone and 2-MeTHF, are discussed as well.
引用
收藏
页码：1601 / 1612
页数：12
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