An efficient one-pot three-component synthesis of α-amino nitriles via Strecker reaction catalysed by bismuth(III) nitrate

被引：16

作者：

Mansoor, S. Sheik ^{[1
]}

Aswin, K. ^{[1
]}

Logaiya, K. ^{[1
]}

Sudhan, S. P. N. ^{[1
]}

机构：

[1] C Abdul Hakeem Coll, Dept Chem Res, Melvisharam 632509, Tamil Nadu, India

来源：

JOURNAL OF SAUDI CHEMICAL SOCIETY | 2016年 / 20卷

关键词：

Bismuth nitrate; Amino nitriles; One-pot synthesis; Strecker reaction; TRIMETHYLSILYL CYANIDE; ORGANIC-SYNTHESIS; HIGHLY EFFICIENT; CARBONYL-COMPOUNDS; ACID DERIVATIVES; AMINONITRILES; REAGENT; ALDEHYDES; MILD; CONDENSATION;

D O I：

10.1016/j.jscs.2012.10.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient and efficient one-pot method for the synthesis of a variety of a-amino nitriles from aldehydes, amines and trimethylsilyl cyanide (TMSCN) in the presence of a catalytic amount of Bi(NO3)(3) at room temperature in acetonitrile (MeCN) is described. The significant features of this method are simple work-up procedure, inexpensive and non-toxic catalyst, shorter reaction times and excellent product yields. The catalyst Bi(NO3)(3) can be reused. The reusability of the catalyst has been studied for the synthesis of various amino nitriles. (C) 2012 Production and hosting by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

引用

页码：S202 / S210

页数：9

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